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密级 公开 学号 050208 此京石油祂工修魂 BEIJING INSTITUTE OF PETROCHEMICAL TECHNOLOGY 毕业设计（论文） 2, 6-蔡二甲酸二甲酯的合成 院係、部）: 名: 级: 业： 化学工程学院 徐海涛 2005 级化学工程与工艺 指导教师: 靳海波/教授 2009年06月01日?北京 摘要 蔡二甲酸二甲酯(DM?2,6?NDC)是合成功能聚合物PEN、PBN以及液晶 聚合物LCP的重要屮间体，?其合成技术的研究一直是国内外屮间体合成和功能材 料领域研究的重点和热点。木论文研究选用2,6-蔡二甲酸和甲醇作酯化反应，浓硫 酸、硫酸亚铁、硫酸铁分别作为催化剂，通过多组对比性试验得出适宜的反应工艺 条件是醇酸摩尔比为40:1,酯化温度为160°C,酯化吋间为2小吋，催化剂为浓硫 酸，催化的加入量为2,6-蔡二甲酸质量的7%。在适宜的条件下，酯化过程的收率 为88%以上，并月工艺条件具冇良好的重现性，是立足国内优势开发功能聚合物的 首选技术路线。 关键词：酯化，2,6-蔡二甲酸二甲酯，PEN,合成 Abstract Dimethyl-2,6-naphthalenedicarboxylate(DM-2,6-NDC) is of functional polymer PEN, PBN, as well as LCP liquid crystal polymer. Therefore, Dimethyl-2,6-naphthalenedicarboxylate synthesis has aroused great interest, and a great deal of relevant research have achieved certain results. The synthesis condition of dimethyl-2,6-naphthalenedicarboxylate was studied in this pape匸 The effect of catalyst concentration, molar ratio of 2,6 - naphthalene dicarboxylic acid and methanol, esterification time and esterification temperature were discussed using sulfuric acid, ferrous sulfate, ferric sulfate as a catalyst, respectively. According to the experimental results, the suitable process conditions was obtained as follows, molar ratio of 40:1, esterification temperature of 160°C, the esterification time was 2 hours, the catalyst for the concentrated sulfuric acid and its adding 2,6 ? naphthalene dicarboxylic acid 7% of the quality The highest yield of the esterification process was 88% under this conditions. KEY WORDS： esterification, dimethyl-2,6-naphthalenedicarboxylate, PEN, Synthesis 目 录 TOC \o 1-5 \h \z HYPERLINK \l bookmark4 \o Current Document \h 第一章前言 1 HYPERLINK \l bookmark6 \o Current Document \h 1.1研究背景与意义 1 HYPERLINK \l bookmark8 \o Current Document \h 1.2文献综述 2 121磷餌酸催化合成2, 6-蔡二甲酸二甲酯 2 122硅餌酸催化合成2, 6-蔡二甲酸二甲酯 2 1.2.3硫酸亚铁催化合成2, 6-蔡二甲酸二甲酯 3 HYPERLINK \l bookmark10 \o Current Document \h L3基本内容，拟解决的主要问题 3 HYPERLINK \l bookmark12 \o Current Document \h 1.4研究方法 3 HYPERLINK \l bookmark14 \o Cur