有组织排放挥发性有机物监测方法研究以溶剂使用源为例.docVIP

有组织排放挥发性有机物监测方法研究:以溶剂使用 源为例 王红丽巴 景盛翱，王倩，黄成，楼晟荣，乔利平，李莉 国家环境保护城市大气复合污染成因与防治重点实验室，上海市环境科学研究院，上海 200233 摘要：本研究以上海2家修造船企业、3家汽车制造企业、2家大型涂料生产企业、1家大 型油墨主产企业以及1家大型包装印刷企业为例，研究不同监测方法刈溶剂使用源冇组织排 放废气VOCs监测的适用性；并在此基础上探讨溶剂使用源排放VOCs的组成特征。结果表 明，采用Summa罐可以很好的采集和储存溶剂使用源排放的有机物，废气经Summa罐采 集储存一周内，其中的非甲烷总烧(NMHC)浓度与企业现场测试结果一致性很好，二者相 关系数高达0.99,比值为1.04±0.09。釆用气相色谱■氢离子火焰/质谱(GGFID/MS)联用技 术分析Summa罐采集的废气，可以定量分析的VOCs组分占NMHC的60%左右(以碳计)； 不同溶剂使用过程排放的NMHC中可定量组分的比例存在一定的差异，变化范围从29%到 92%；在可定量VOCs组分中，芳香姪和含氧VOCs是主要组成。研究结果对于研究溶剂使 用源排放VOCs的物质清单有一定支撐作用。 关键词：挥发性有机物，溶剂使用，非甲烷总炖 监测 Volatile Organic Compounds (VOCs) Measurements in Industrial Emissions: Case Study of Solvent Use Emissions in Shanghai, China WANG-Hong-li, JING Sheng-ao, WANG Qian, HUANG Cheng, LOU Sheng-rong, QIAO Li-ping, LI Li State Environmental Protection Key Laboratory of Formation and Prevention of the Urban Air Complex, Shanghai Academy of Environmental Sciences, Shanghai 200233, China Abstract: Volatile Organic Compounds (VOCs) measurement is complex due to the various species and chemical reactivity, which is more challcnging under the conditions of industrial exhausts? In this study different measurement methods were employed to monitor VOCs emissions from industrial solvent use and stainless-steel Summa canisters sampling was proved to be suitable for the collection and storage of solvent VOCs emissions for scientific purpose? Non-methane hydrocarbons (NMHC) concentrations of canister samples were measured by GC-FID-MS analysis right after the collection and one week after collection. The results showed good consistency with an linear correlation factor of 1.04±0.09 (2-0.99 ).Measured NMHC can be quantified by VOCs species for about 60% in average by means of GO FID analyses. The value varied from 0.29 to 0.92insamples from i基金项目：国家环保公益项冃(No. 201409008),国家科技支撑计划项冃(No. 2014BAC22B03),国家环境保 护标准项目(No. 2015-17) 作者简介：王红丽(1983?)，女，山西人，wanghl@sacs.sh.cn： HYPERLINK mailto:hongliwang@livc.cnhongliwang@livc.cn *责任作者：王红丽(1983-),女，山西人，高级工程师，博士，主耍从事大气