工业明胶基造纸助留助滤剂的合成及其性能研究有机化学专业论文.docxVIP

英文摘要Synthesis 英文摘要 Synthesis of industry gelatin based papermaking retention and drainage aid and tis performances investigation Organic Chemistry Graduate YUE Li-jun Tutor WANG Bi ABSTRACT Papermaking retention and drainage aid is an important process additive， main function is to enhance filler retention rate and improve drainage performance of pulp，which has great significance for the quality of paper and paper machine operating performance．Along with the people environmental protection consciousness enhancement，the development and application of biomass based retention and drainage aid become a research hotspot．In this paper,the gelatin based retention and drainage aid was prepared by using industrial gelatin extracted from leather waste as raw material， and investigation its retention and drainage performance． Firstly,G-Gel was prepared by using glutaraldehyde as crosslinking agent and Gel as raw material．The results showed that the optimum conditions for the synthesis of G-Gel，the dosage of glutaraldehyde was 1 0％of the quality of Gel，the reaction temperature was 400C，pH value was 7，and the reaction time was 3h．By Ninhydrin colorimetric method determination of Gel and G-Gel primary amine content was 26mmol／1009，9．5mmol／lOOg，respectively．Showed that the crosslinking reaction of glutaraldehyde and Gel has been successfully carried out，and G—Gel crosslinking degree was 63％．The structure of G-Gel and the reaction mechanism were analyzed by fourier infrared spectrum(FT-IR)，ultraviolet spectrum(UV-Vis)and thermo gravimetric analysis(TGA)．IR and UV spectra showed that the formation of Schiff base structure between the primary amino group of Gel and the aldehyde group of glutaraldehyde．Thermogravimetric analysis showed that the crosslinking reaction effective increased thermal stability of G-Gel．Due to the function mechanism of the flocculants is similar to the function mechanism of retention and drainage aid，SO the flocculation performance of G—Gel is studied b