多孔电极材料的新法制备及电催化与分析应用分析化学专业论文.docxVIP

2．在处理好的QCM金电极上，共沉积一层PANI．Pt膜，然后用洗 2．在处理好的QCM金电极上，共沉积一层PANI．Pt膜，然后用洗 液选择性除去PANI，制备了三维多孔铂膜(Plbonu)。用EQCM 监测了电极的修饰过程并结合Sauerbrey方程求出了修饰膜层的 质量。探讨了苯胺与H2PtC]6在酸性、中性以及碱性溶液中共沉积 制备的Ptp0，的催化性能，实验发现酸性条件下制得的％o／Au电 极催化效果最好。基于此，比较了％√Au、PANI。Pt／Au以及 ‰加札电极对H202的催化活性。结果表明，Ptp√Au电极的催化 性能最好，在等质量铂的情况下，‰∥m电极的催化活性较 Ptc04札电极提高了约4．6倍。由此，我们构建了一高灵敏的H202 传感器，O．5 V下PtpoI／Au电极催化H202氧化电流的灵敏度为323 pA cm-2 raM-1，检测限为5 nM(鲫=3)。 3．在处理好的QCM金电极上，于酸性介质中共沉积一层PANI．Pt．Ru 膜，然后用洗液选择性除去PANI，制备了三维多孔铂。钌合金膜 (n-Rl灿)并研究了该修饰电极在碱性溶液中对甲醇的电催化 氧化。结果表明阼R‰∥m电极在碱性溶液中对甲醇的电催化氧 化活性很高，其催化活性比Ptpo以组电极提高了约75％，同时也 是常规电沉积法制备的铂．钌修饰的金电极(Pt．Ru啪／Au)的2．33 倍。此外，Pt．Rup√Au电极的稳定性也比Ptp√Au和Pt．RLlc彻厂Au 电极好。 关键词：聚苯胺；模板法；电化学石英晶体微天平(EQCM)；电催 化氧化；电沉积；生物传感器 Ⅱ AB AB STRACT Porous platinum electrodes have been attracting increasing interest for their unique properties and broad range of applications．Up to now,there are three popular methods for preparing porous platinum electrodes such as templating，free—templating and dealloying．Among the polymer templates，the insulating or inactive substances are usually employed．In this paper,a novel protocol with the conductive polymer polyaniline (PANI)as a template followed by its removal by HN03 or chromosulfuric acid is presented to prepare three··dimensional porous Pt--related film electrodes，and the thus-prepared electrodes are used for construction of high-sensitivity biosensing interfaces and electrocatalytic oxidation of methanol with optimistic results．The studies in this thesis are summarized as follows： 1．Three—dimensional porous platinum(％。r)films are prepared based on Pt electrodeposition on PANI modified glassy carbon electrodes (GCE)followed by selective dissolution of PANl with HN03． Electrochemical quartz crystal microbalance(EQCM)was used to in situ monitor the fabrication processes and study the interaction between H2PtCl6 and PANI．The EQCM data suggest that the PANI-I-12PtCl6 interaction involves redox and coordination reactions，depending on the Based on these observations，we propos