夹杂对自来水环境下304不锈钢腐蚀及金属离子溶出的影响Effectof.PDFVIP

夹杂对自来水环境下304 不锈钢腐蚀及金属离子溶出的影响 王永利，马利，熊良银，刘实 中国科学院金属研究所 特殊环境材料部，沈阳110016 摘 要 采用二苯碳酰二肼比色法分析测试了不同状态的 304 不锈钢样品在自来水环境下的 Cr6+溶出规律，并对样品进行了微观组织分析。结果表明，不同状态的不锈钢材料中Cr6+溶 出量差别很大，材料中的球状氧化物夹杂尺寸越大、数目越多，对应的Cr6+溶出量越高。采 用粉末烧结的方法在金属中引入Cr O 夹杂和Cr O +MnO 复合夹杂并测试Cr6+ 的溶出规律，结 2 3 2 3 2 果显示MnO2 的添加大幅度提高了Cr6+ 的溶出量，且氧化物添加量越多，Cr6+溶出量越大。证 实了Cr/Mn 复合氧化物夹杂分布（尺寸和密度）对不锈钢样品Cr6+溶出量有重要影响：在含 Cl 的水环境下，Cr/Mn 复合氧化物夹杂既是Cr3+来源，又提供了氧化剂使Cr3+转化为Cr6+ 。 这表明通过控制铸件或粉末冶金件中的Cr/Mn 复合氧化物夹杂的尺寸和数目，可大幅度降低 材料Cr6+ 的溶出量。 关键词：304 不锈钢 Cr6+ 夹杂 Cr/Mn 复合氧化物 中图分类号： 文献标识码： 文章编号： Effect of Inclusions on Corrosion Behavior and Metallic Ion Dissolution of Stainless Steel 304 in Simulated Tap Water WANG Yongli, MA Li, XIONG Liangyin, LIU Shi Materials for Special Environment Department, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China ABSTRACT Stainless steel 304 is being widely used as the pipe or tap for water supply, and the dissolution of 6+ Cr ions from materials into tap water is one of the critical indicators of safety assessment. In present work, stainless steel 304 specimens with different states, including pipe, bar, plate, casting, and powder metallurgical product, were soaked in simulated tap water for 22 days, and the 6+ concentration of Cr ions in the soaking solution was determined by the diphenylcarbazide method using a spectrophotometer V-1800PC. Metallography analysis was performed to observe the crystalline morphology, phase composition, and inclusion distribution of different 304 steel 6+ specimens. The results showed that the variations of the integrations of dissolved Cr ions with 定稿日期： 第一作者：王永利，女，1984年