电化学氧化法处理海洋油田废水-工业水处理杂志.PDF

2002 年6 月 Jun., 2002 第22 卷第6 　　　　　　　　　　Industrial Water Treatment 　　　　　　　　　　　Vol.22 No.6 1 2 3 李海涛, 朱其佳 , 祖荣 (1.广州有色金属研究院, 广东 广州　510651; 2.中国海洋石油南海西部公司, 广东 湛江　524057;3.振海油田化学公司, 广东 湛江　524057) 　　[] , , COD 。, COD 。, , (Electrochemical Oxidation Index)0.228, (Electrochemical Oxygen Demand) 1.794 g/g( ), 75.3%, NaClO , , COD 。 　　[] ;; 　　[] 703.1;O646　[] A　[] 1005-829 (2002)06-0023-03 Electroox idat ive degradation of wastewat er from t he oceans recover pet roleum terminal station 1 2 3 LI Hai-tao , ZHU Qi-jia , ZU Rong (1.Guangzhou Research Institute of Non-f errous Metals, Guangzhou 510651, China; 2.The Ocean Petroleum West Co.Ltd.of South China, Zhanj iang 524057, China; 3.Zhenhai Oil ield Chemistry Comp any CONH W, Zhanj iang 524057, China ) Abst ract :There is benzene derivation and multiring aromatic hydrocarbon with NaCl in the wastewater which comes from the oceans recover petroleum terminal station.It is very difficult to lower its COD (Chemical Oxy- gen Demand)value down to national regular limitation (Grade 1:100 mg/L)with biochemical degradation method.The COD of this wastewater can be reduced to less than 100 mg/L by electrochemical oxidizing degra- dation.It uses titanium substrate coated by Ru, Ir, Mn, Sn, Ti multiple oxides as anodes and Ti as the cath- odes in undivided electrolysis cells.The electrochemical oxidation index is 0.228, the electrochemical oxygen de- mand is 1.794 g/g (Organic), and the degree of electrochemical oxidation is 75.3%.After the electrochemical oxidation of wastewater, by the synergistic effect of NaClO with the residual organics in bulk, the COD of was