水煤浆气化炉协同处置煤液化残渣的PAHs排放特征.PDFVIP

中国环境科学 2017,37(10) ：3845~3852 China Environmental Science 水煤浆气化炉协同处置煤液化残渣的 PAHs 排放特征 * 李雪冰,李 丽 ,黄泽春,闫大海,于泓锦,王 宁 ( 中国环境科学研究院固体废物与污染控制技术研究所,北京 100012) 摘要：采用现场工程试验方法对德士古水煤浆气化炉协同处置煤液化残渣(CLR)过程中多环芳烃(PAHs) 的排放特征及环境风险进行了 系统研究,通过对空白工况(不混磨 CLR 制浆)和协同处置工况(混磨 15%CLR 制浆)下,气化炉内温度、压力与合成气组分变化及所有排 放节点固态液态气态排放物中 16 种 PAHs 含量及毒性当量浓度分析,评估 CLR 协同处置过程中 PAHs 的环境风险及该技术的可行性. 结果表明:德士古水煤浆气化炉协同处置 15%液化残渣过程对气化炉自身产气量及压力无显著影响,炉内温度升高 5~11℃,对 H2 和 CO 的产生具有促进作用;协同处置过程造成部分气态排放产物和液态排放物中 PAHs 含量增加,但增幅很小,且毒性当量浓度也远低于标准 限值,新增环境风险很小;协同处置过程使固态排放产物中 PAHs 含量显著增加,但总毒性当量浓度依然较低, 固态产物中 PAHs 的排放风 险在可接受的范围内. 关键词：水煤浆气化炉；协同处置；煤液化残渣；多环芳烃；排放特征 中图分类号：X705 文献标识码：A 文章编号：1000-6923(2017)10-3845-08 Emission characteristics of polycyclic aromatic hydrocarbons during co-processing of coal liquefaction residue in * coal-water slurry gasifier. LI Xue-bing, LI Li , HUANG Ze-chun, YAN Da-hai, YU Hong-jin, WANG Ning (Research Institute of Solid Waste Management, Chinese Research Academy of Environmental Sciences, Beijing 100012, China). China Environmental Science, 2017,37(10)：3845~3852 Abstract ：Field tests were conducted to research the emission characteristics and environmental risks of polycyclic aromatic hydrocarbons (PAHs) during co-processing of coal liquefaction residue (CLR) in Texaco coal-water slurry gasifier. Comparing the differences between blank condition (without mixing CLR in the slurry) and test condition (15% CLR were mixed into the slurry), the changes of temperature, pressure and syngas composition in the gasifier were recorded, the toxicity equivalent concentration of 16 kinds of PAHs in all the solid, liquid and gas emissions were analyzed to evaluate the feasibility and environme