偶联剂对氧化铁红粉体的表面改性-表面技术.PDFVIP

第43卷摇 第1期 摇 摇 摇 表面技术 摇 摇 2014年02月 SURFACE TECHNOLOGY ·59 · 試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試 偶联剂对氧化铁红粉体的表面改性 沈远,刘京雷,侯峰,徐宏,任衍伦 (华东理工大学 机械与动力工程学院,上海200237) 摘摇 要: 目的摇 研究硅烷偶联剂KH鄄560 与钛酸酯偶联剂对氧化铁红粉体的改性效果。 方法摇 采用硅烷 偶联剂KH鄄560 与钛酸酯偶联剂对超细氧化铁红粉体进行改性,同时与未改性的粉体进行比较,对比研究 粉体的亲油化度、吸油值、粒度分布、疏水性及分散情况。 结果摇 改性后,氧化铁红粉体的细化程度、团聚 状况都有一定的改善。 粉体由改性前的亲水性变为亲油性,在有机体系中的分散性能得到了提高。 结论 硅烷偶联剂KH鄄560 与钛酸酯偶联剂都能有效改善铁红粉体的表面性能,而钛酸酯偶联剂的改性效果优 于KH鄄560。 关键词:氧化铁红;表面改性;改性剂;亲油性 中图分类号:TQ622摇 摇 摇 文献标识码:A摇 摇 摇 文章编号:1001鄄3660(2014)01鄄0059鄄04 Surface Modification of Iron Oxide Red Powder Using Coupling Agent SHEN Yuan,LIUJing鄄lei,HOUFeng,XUHong,REN Yan鄄lun (School of Mechanical and Power Engineering,East China University of Science and Technology,Shanghai200237,China) ABSTRACT:Objective To study the modification effects of iron oxide powder by the silane coupling agent KH鄄560 and titanate coupling agent. Methods Fine iron oxide red powder after modification was comparedwith the unmodified powder. Lipophilic de鄄 gree and oil鄄absorbed valuewere studied,and the modification effectswere analyzed by CILAS particle size distribution analyzer, SEM andcontactanglemeters. ResultsThedegreeofrefinementof ironoxideredpowderwaseffectively improvedandtheagglom鄄 erates of the powder were reduced,the powder was changedfrom hydrophilic into lipophilic after modification,and the dispersing performance of the powderintheorganicsystemwasimproved. ConclusionThetwomodifierscouldeffectively improvethesurface performance of thefine iron oxide red powder. Besides,the modification effect of titanate coupling agent was better than that of KH鄄560. KEY WORDS:iron oxide red;surface modification;modifier;lipophilic property 摇 摇 超细粉体具有粒度小、比表面积大、表面活性强