仿生支撑液膜法制备硫化锌自组装纳米球链BiomimeticSelf-assembly.PDFVIP

2005 年第 63 卷 化 学 学 报 Vol. 63, 2005 第 16 期, 1479～1482 ACTA CHIMICA SINICA No. 16, 1479～1482 ·研究论文· 仿生支撑液膜法制备硫化锌自组装纳米球链 孙冬梅 a 吴庆生*,a 朱 勇 a 丁亚平 b (a 同济大学化学系 上海 200092) (b 上海大学化学系 上海 200436) 摘要 采用了一种全新的化学仿生方法——载体支撑液膜法制备 ZnS 纳米球链. 常温常压条件下, 利用含邻菲罗啉载 体的支撑液膜(SLM)反应体系选择性传输 Zn2＋至膜另一侧, 在 SLM 模板作用下, 控制结晶位点, 定向结合阴离子, 加 上局部过饱和及界面成核的影响, 成功制备出由 8～30 nm 纳米粒子自组装的直径范围为 250～300 nm ZnS 球链. 由 XRD 和 TEM 的结果显示, 其结构为立方闪锌矿, 晶格常数为a ＝0.5390 nm. 本文还对其荧光性质及产物形成机理进行 了初步探讨. 关键词 支撑液膜; 仿生; ZnS; 纳米球; 链状 Biomimetic Self-assembly Synthesis of ZnS Chain-like Nanospheres with Supported Liquid Membrane SUN, Dong-Meia WU, Qing-Sheng*,a ZHU, Yonga DING, Ya-Pingb a ( Department of Chemistry, Tongji University, Shanghai 200092) (b Department of Chemistry, Shanghai University, Shanghai 200436) Abstract A novel synthesis method of ZnS chain-like nanospheres by supported liquid membrane system has been investigated. The system, with o-phenanthroline as a mobile carrier, can selectively transport zinc ions to the other side of the membrane. Nucleation process was under the control of SLM template effect by directionally combining anion, local super saturation solution and the interfacial microenvironment. XRD and TEM data indicated that the crystal has cubic structure of blende with cell constant of a ＝0.5390 nm in the range of 250～30