聚合物改性水泥水化程度测定方法比较.pdfVIP

· 1116 · 硅 酸 盐 学 报 2013 年 第41 卷第8 期 硅 酸 盐 学 报 Vol. 41 ，No. 8 2 0 1 3 年 8 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY August ，2013 DOI ：10.7521/j.issn.0454–5648.2013.08.15 聚合物改性水泥水化程度测定方法比较 王培铭，彭 宇，刘贤萍 ( 同济大学，先进土木工程材料教育部重点实验室，上海 201804) 摘 要：介绍了当前测试水泥水化程度的几种方法：水化热法、化学结合水法、氢氧化钙含量测定法和背散射电子图像分析法。比较了这些方法对聚 合物改性水泥水化程度测试的适用性和局限性。聚合物由于改变了水泥水化进程和水化产物的组成、其本身热分解的温度又与水化产物相近，在多种 测试方法中都会对水泥水化程度测试带来干扰，使得测试结果存在较大的偏差。而背散射电子图像分析法是基于某一龄期未水化颗粒占原始颗粒的比 例来表征水化程度的，而与水化过程和水化产物的组成无关，是测试聚合物存在下水泥水化程度的一种可靠方法。 关键词：聚合物改性水泥；水化程度；测试方法；比较；背散射电子图像分析法 中图分类号：TU528 文献标志码：A 文章编号：0454–5648(2013)08–1116–08 网络出版时间：2013–08–01 17:57:43 网络出版地址：/kcms/detail/11.2310.TQ1757.015.html Comparison of Methods for Determination of Hydration Degree of Polymer Modified Cement Paste WANG Peiming，PENG Yu ，LIU Xianping (Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China) Abstract: Four methods for the determination of cement hydration degree, i.e., hydration heat, chemical-bond water, Ca(OH)2 quan- titative measurement and backscattered electronic image analysis (BEI), were introduced. The suitability and limitations of these methods for polymer modified cement paste (PMC) were discussed. When some methods were used to examine the cement hydration degrees of PMC, the interference and large deviations could be imported due to the polymer change of hydration process and hydrated products and the similarities of thermal decomposition temperature between polymers and hydrated products. The BEI as a method based