纸浆悬浊液中疏水性胶体物质与阳离子高分子凝集剂.pdf

紙漿懸濁液中疎水性膠體物質與陽離子高分子凝集劑間凝集反應的可視化 紙漿懸濁液中疏水性膠體物質與陽離子高分子凝集劑間 凝集反應的可視化 蘇裕昌＊ Visualization of the Interaction among Hydrophobic Colloidal Substances and Cationic Fixing Agents in a Pulp Suspension Yu-Chang Su ＊ Summary By establishing a dying technology of the hydrophobic colloidal substances (HCS) with fluorescent dye and labeling cationic polymer with Fluorescein-4-isothiocyanate, visualization of HCS and cationic polymer is achieved. The interactions between HCS and cationic fixing agents in pulp suspension were visualized by a confocal laser scanning microscopy. Observation results showed that in the fiber suspensions after addition of the cationic polymer, HCS were mainly adsorbed on the external fibrils of fibers. In addition, absorption behaviors of HCS were dependent on the cationic polymer species added. Results confirmed that this technique can be applied for the elucidation of adsorption behaviors of HCS of paper stock. It also can be applied as a countermeasure of fixing sticky materials with cationic polymers. Key words: hydrophobic colloidal substances, cationic fixing agents, stickies control, fluorescent dye, labeled with Fluorescein-4-isothiocyanate. 一、緒言 帶出系統(エッサーet al.,2005) ( Holik, 2006) (蘇，2012b) (村 田 etal.,2012) 。一般在生物學、或細胞學的研究上常以螢光 近年來，由省資源、或環境保護、成本的觀點， 紙料中 染 料 做 為 疎 水 性 物 質 的 染 色 ， 使 用 流 式 細 胞 儀 (flow DIP 的高配合率在造紙工業中有逐年增加的趨勢。但是，廢 cytometry) 、或螢光的強度等進行微細為粒子數目的定量，其 紙的品質逐年有顕著的降低，且廢紙中所含之黏著物造成的 方法極為複雜、且有精確度考量。目前沒有方法能完全滿足 問題在紙機上頻發的趨勢。 因此， 黏著物的處理對策日益