生活污泥与煤混烧及热解特性.pdf

第 11卷　 第5 期 环 境 工 程 学 报 Vol. 11,No.5 2 0 1 7 年 5 月 Chinese Journal of Environmental Engineering May 2 0 1 7 生活污泥与煤混烧及热解特性 1,∗ 2 1 陈繁荣 ,孙鸣 ,高晓明 1.延安大学化学与化工学院,陕西省化学反应工程重点实验室,延安 716000 2.西北大学化工学院,西安 710000 摘　 要　 采用热重分析法,对生活污泥与煤以1∶1质量比混合的试样进行燃烧及热解实验研究,重点分析了升温速率对其热 解及燃烧特性的影响,为煤泥混烧及热解技术的工业化应用提供理论支持。 结果表明:煤泥混合样燃烧失重分为4 个阶段,混 -1 -1 燃过程中污泥与煤共同影响着混合试样的燃烧特性,随着升温速率从 15 ℃ ·min 增加到50 ℃ ·min ,其可燃性指数 C增 幅达60%和综合燃烧特性指数S 提高了4倍多,燃烧性能得到明显提高;煤泥混合样的热解失重分为2个阶段,各阶段热解的 挥发份最大析出速率(dw/ dt) 及挥发分析出特性指数D 均随升温速率的升高而大幅增大,且试样总的挥发综合释放指数 D max -8 -3 -2 -8 -3 -2 从0.0817 ×10 K ·min 增大到5.868×10 K ·min ,可见升温速率越高,煤泥混合物的热解性能越好。 关键词　 煤泥混合物;燃烧;热解;热重分析 中图分类号　 X705　　 文献标识码　 A　　 文章编号　 1673-9108(2017)05-3161-05　　 DOI　 10.12030/ j.cjee.201601231 Combustion and pyrolysis characteristics of sewage sludge and coal 1,∗ 2 1 CHEN Fanrong ,SUN Ming ,GAO Xiaoming 1.Shaanxi Key Laboratory of Chemical Reaction Engineering, School of Chemistry and Chemical Engineering, Yan′an University, Yan′an 716000,China 2.School of Chemical Engineering,Northwest University,Xi′an 710069,China Abstract　 In order to provide theoretical supportfor industrial application,combustion and pyrolysis characteris- tics of sewage sludgewith coalwere studied using a thermogravimetric analyzer in equal massratio. The influence of heating rate on the combustion and pyrolysis characteristicswas emphatically analyzed. The results showed that the combustion loss of sludge-coal mixed fuel was divided into four stages and the combustion characteristicswere affected by both sludge and coal during the combustion process. When the heating rate increased from 15 to 50 -1 ℃ ·min ,t