质子交换膜燃料电池钛基双极板多弧离子镀TiN膜-中国有色金属学报.PDF

第 21 卷第 1 期 中国有色金属学报 2011 年 1 月 Vol.21 No.1 The Chinese Journal of Nonferrous Metals Jan. 2011 文章编号：1004-0609(2011)01-0159-06 质子交换膜燃料电池钛基双极板 多弧离子镀 TiN 膜的腐蚀行为 段良涛, 张东明, 郭 路, 王再义 (武汉理工大学 材料复合新技术国家重点实验室，武汉 430070) 摘 要：为了增强钛金属双极板的耐腐蚀性能，通过多弧离子镀膜技术在钛基双极板表面镀一层 TiN，对薄膜的 表面形貌，晶体结构与耐腐蚀性能之间的关系进行研究。结果表明：镀有 TiN 膜样品的耐腐蚀性能比未镀膜样品 的有明显提高，其腐蚀电流密度最低可达201 μA/cm2 。测试其动电位极化曲线和恒电位极化曲线发现，样品的耐 腐蚀性能与薄膜的晶体结构以及表面颗粒和孔洞有密切的关系。适当的晶体择优取向有利于提高样品的耐腐蚀性 能，而表面的颗粒和孔洞对样品的长期耐腐蚀性有很大影响。通过能谱分析发现，腐蚀后的样品表面发生了氧化。 关键词：质子交换膜燃料电池；钛基双极板；多弧离子镀；耐腐蚀性；TiN 膜 中图分类号：TM911.4 文献标志码：A Corrosion behavior of TiN-coated titanium as bipolar plates for PEMFC by multi-arc ion plating DUAN Liang-tao, ZHANG Dong-ming, GUO Lu, WANG Zai-yi (State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China) Abstract: In order to enhance the corrosion resistance of Ti bipolar plates, TiN films were deposited on titanium as bipolar plates for proton exchange membrane fuel cells (PEMFC) by adjusting the nitrogen pressure. The relationships among the surface morphology, crystal structure and corrosion resistance of the film were investigated. The results show that the TiN-coated titanium exhibits higher corrosion resistance than uncoated titanium, the lowest current density was 201 μA/cm2 . Potentiodynamic and potentiostatic tests show that the corrosion resistance of TiN-coated sample is greatly associated with the crystal structure and particles and holes on the surface of the film. The suitable gro