氮化钛多孔陶瓷的制备孔隙结构调控及其力学导电性能-硅酸盐学报.PDFVIP

第 46 卷第 9 期 硅 酸 盐 学 报 Vol. 46 ，No. 9 2 0 1 8 年 9 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY September，2018 DOI ：10.14062/j.issn.0454-5648.2018.09.10 氮化钛多孔陶瓷的制备、孔隙结构调控及其力学、导电性能 陈 斐，黄 梅，沈 强，张联盟 (武汉理工大学材料复合新技术国家重点实验室，武汉 430070) 摘 要：采用凝胶注模成型工艺制备 TiN 多孔陶瓷，研究了固含量、烧结温度对 TiN 多孔陶瓷物相组成、微观结构、孔隙率 和孔径分布的影响，以及 TiN 多孔陶瓷孔隙结构与其力学、电学性能的关联。结果表明：随着固含量和烧结温度的升高，TiN 多孔陶瓷孔隙分布均匀，孔径尺寸和孔隙率缓慢下降，其开气孔率变化范围为 41.8%~60.0% 。随着孔隙率的降低及烧结温度 的升高，TiN 多孔陶瓷抗弯强度及电导率分别由14.2MPa 和7.9×103 S/m 逐渐增大到34.6 MPa 和23.1×103 S/m，这是由于Y TiO 2 5 液相的产生，促进了晶粒生长及孔壁连接。 关键词：氮化钛多孔陶瓷；力学性能；电学性能；凝胶注模成型 中图分类号：TB321 文献标志码：A 文章编号：0454–5648(2018)09–1244–06 网络出版时间：2018–07–02 Fabrication, Pore Structure and Mechanical / Electrical Properties of Porous Titanium Nitride Ceramics CHEN Fei, HUANG Mei, SHEN Qiang, ZHANG Lianmeng (State Key Lab of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China) Abstract: Porous TiN ceramics were prepared via gel-casting. The effects of solid loading and sintering temperature on the phase composition, microstructure, porosity and pore size distribution of the prepared porous TiN ceramics were investigated, and a relationship between pore structure and mechanical/electrical properties was analyzed. The results show that the pore distribution of porous TiN ceramics becomes uniform, the pore size decreases slowly as well as the porosity varies from 41.8% to 60.0% when solid loading and sintering tempera