太阳能电池中几种新型敏化剂.pdfVIP

化 学 与 黏 合 2011 年第33 卷第3 期 CHEMISTRY AND ADHESION ·59 · 太阳能电池中的几种新型敏化剂 蔡冬英，乔庆东 （辽宁石油化工大学石油化工学院，辽宁 抚顺 113001） 摘要：染料敏化太阳能电池（DSSC）是近几十年来发展起来的新型的高效率、低成本的电池，而染料敏化剂的性能对DSSC 的光电转换效率有重要的影响。介绍了敏化剂对TiO 的敏化作用机理，并着重概述了染料太阳能电池中的几种新型敏化剂的 2 设计合成，在此基础上，指出研制高光电转换效率、成本低廉、环境友好、具有良好稳定性的敏化剂是未来敏化剂的研究重点。 关键词：染料敏化太阳能电池；敏化剂；光电转换效率 + 中图分类号：TM 914.4 2 文献标识码：A 文章编号：1001- 0017 （2011）03- 0059- 07 Several New Sensitizers of Dye-sensitized Solar Cells CAI Dong-ying and QIAO Qing-dong （College of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China） Abstract ：Dye-sensitized solar cells （DSSC）, as a new type of solar cells developed over the past decade, are regarded as the low cost and high- efficiency photovoltaic cells. The performances of the sensitizers have considerable influences on the photoelectric conversion efficiency of the DSSC. The mechanism of action of sensitizer for titanium dioxide is introduced briefly. Furthermore, the designs of several new sensitizers are especially re － viewed. Based on these, it is pointed that the future study on sensitizers will be focused on high photoelectric conversion efficiency, low cost, environ － ment friendly and good stability. Key words: Dye-sensitized solar cells; sensitizer; photoelectric conversion efficiency 染料敏化太阳能电池的关键问题之一在于敏 引 言 化染料的选择，其中染料性能的优劣将直接影响染 料敏化纳米二氧化钛太阳能电池的光电转换效率 能源问题是制约世界经济发展的首要问题，太