城市污水处理厂挥发性有机恶臭污染物的来源及感官定量评价学位.docxVIP

城市污水处理厂挥发性有机恶臭污染物的来源及感官 定量评价一学位论文 暨南大学硕士学位论文城市污水处理厂挥发性 有机恶臭污染物的來源及感官定量评价 摘要 本论文通过联合使用预浓缩-气相色谱-质谱仪(GC/MS)与电子鼻气味指纹仪 两种分 析技术，选取广州市典型的城市污水处理厂进行外场观测和模拟试验，研究 了城市污水处 理厂挥发性恶臭有机物(MVOC)的化学组成、含量和感官指纹等污染特征，探 讨了恶臭 污染的感官定量评价方法,获得如下研究结论： 1?城市污水处理厂检出烷炷、烯炷、芳香怪、卤代烧、含硫有机物和含氧有 机物等6 类共80种V0C化合物，包括54种MV0C成分,其含量与处理工艺段密切相 关,污泥脫 3 水机房的MV0C含量旳为显著，各采样点污染物浓度变化范围为： 132.36~905?96 ug/m 。 苯乙烯、苯、甲苯、邻二甲苯、间/对二甲苯和乙苯等苯系物、二硫化碳、 甲硫醛、拨基硫 为该类污染源排放的分子标志物。 2?通过分析MVOC组分浓度与感官气味指纹Z间关系，优选出电子鼻指纹仪 的 T70/2 型传感器为该污水厂MVOC旳为敏感的传感器类型。 对各污水处理单元有机恶臭污染的感官指纹特征进行分析，初步建立了 MVOC 关 2 键化学组分的含量与感官气味之间的关系评价模型，所建模型的R均＞85%, 彼此间显示 出很好的相关性。 4?采用PCA和DFA结合的分析方法研究了各污染源样品之间的差界性和 周边环境的 恶臭气味来源，发现除污泥浓缩池外，其他各源恶臭气味的感官指纹较为相 似。污水厂周 边环境点恶臭气味主要来源于生化池工艺，定性识别率为86. 4%~100%。 5.通过MVOC关键化学组分的含量与感官气味之间的定量关系模型,预测了 周边环 境的MVOC化学组分浓度，发现模型预测浓度与实际测量结果的谋差范圉为 28. 1%~50? 7%o 关键词:恶臭污染，挥发性恶臭有机物，感官评价，电子鼻，城市污水处理厂I 暨南大学硕士学位论文城市污水处理厂挥发性有机恶臭污染物的来源及感官定 量评价 Abstract The chemical compo nents analysis met hod of pre-concentration/thermal desorption/gas chromatography coupled with mass spectrometer(GC/MS)and the odor fingerprint analysis method of an electronic nose were established to measure the air samples of Malodorous Volatile Organic CompoundsMVOCs emitted from a typical municipal sewage treatment plant in Guangzhou. By field observation and laboratory Simulation experiments, the chemical composi tions and concentralions of the MVOCs samples were investigated, as well as the pollution characteristics of their sensorial odor fingerprints. In addition, the method of sensory quantitative assessment was explored. The results are showed as fol lowing: 80 volatile organic compounds(VOCs)were dctccted in the studied plant, including alkanes, alkenes, aromeitic hydrocarbon，halogenated hydrocarbons， volatile sulphur compounds (VSCs)and oxygen-containing hydrocarbons. 54 MVOC species were identified with their composition and concentration closely related with the processing type. Among the six processing units,dehydration room showed the highest level of detected MVOCs? The VO