内陆输送过程中沙尘单颗粒类型及其非均相反应.PDF

2008,28(3) 193~197 China Environmental Science 1 1* 2 1 1 , , , , (1.(), ,1000832.,, 100093) 2004 2~3 3 .3 ,,. 481 ,,8 ,SiCaSFe. ,, SO2 ,,Ca. X513, P402 A 2008 Individual dust particles of long-range transport over continent of China: types and sulfuric heterogeneous reactions. LI Wei-jun1 1* 2 1 1 , SHAO Long-yi , YU Hua , WANG Wei , YANG Shu-shen (1. State Key Laboratory of Coal Resources and Safe Mining, Department of Resources and Earth Sciences, China University of Mining and Technology, Beijing 100083, China 2. State Key Laboratory of Vegetation and Environmental Change, Institute of Botany, Chinese Academy of Sciences, Beijing 100093, China). China Enviromental Science, 2008,28(3)193~197 Abstract Dust samples were collected from three Asian dust storms in Beijing during February and March 2004. The dust particles originated from the Gobi desert in northern and northwestern regions of China and Mongolia, were transported to downstream areas over the continent. 481 individual dust particles were analyzed and classified into 8 different classes using scanning electron microscopy with X-ray energy spectra. The major classes of dust particles were defined as follows: “Si-rich”, “Ca-rich”, “S-rich”, and “Fe-rich”. The Al-S-Ca ternary plot and comparison with dust particles collected around Taklamakan, Hohhot and Dunhuang, indicated that the dust particles were chemically modified during long range transport. The Ca-rich particles offered a favorable interface for heterogeneous chemical reactions with acidic gas SO2 emitted by anthropogenic sources. The heterogeneous chemical reactions involving SO2 led to the modification of parts of the surfaces of some dust particles. Key words