方铅矿高碱浮选流程的电化学-矿冶工程.PDF

22 1 矿　冶　工　程 Vol.22 №1 2002 3 MININGAND METALL RGICAL ENGINEERING March 2002 ① 1 1 1 1 2 顾帼华,胡岳华,邱冠周, 王　晖, 王淀佐 (1. , 410083;2., 100088) 　:, 。:pH12.5, E h 0 2- 2- 0 0 0.17 V , S HPbO , HPbO , S , S ;、。 (DDTC)。 DDTC (PbD )0 ～0.2 V, , DDTC 2 , PbD , -0.9～0.6 V 。 2 :;;; Electrochemistry of Galena in Hight Alkaline Flotation 1 1 1 2 GU Guo-hua ,HU Yue-hua ,QIU Guan -zhou ,WANG Dian-zuo (1.Dep artment of Mineral Engineering , Centra l South University , Changsha,Hunan,410083 China ;2.Beij ing General R e- search Institute f or Nonf errous Metals, Beji ing , 100088, China ) Abstract:Electrochemical behaviour is studied of alena in collectorless or collector flotation system,especially in hi h alkalin- 0 - ity media(pH=12.8).It has been shown that at pH12.5 and E h0 .17 V,S and HPbO2 are oxidation products on the surface of alena, and the former is excessive due to the latters dissolution.The excess sulfur has hydrophobic effect, which is advanta eous to alena flotation.At the same time, sphalerite and pyrite are depressed due to their overoxidation .Di- ethyldithiocarbamate(DDTC)is the most suitable collector for alena and the suitable potential at which DDTC and alena react each other to form PbD ran es from 0 to 0.2 V.Moreover, DDTC can depress the surface overoxidation of alena surface.Al- 2 so,the study has shown that in the ran e of -0.9 to 0.6 V, the hydrophobic PbD2 can be firmly adsorbed on the surface of alena