酸析法回收钴铜矿浸出液中的铜的结果与讨论-有色金属冶炼部分.DOCVIP

doi：10.3969/j.issn.1007-7545.2017.04.002 doi：10.3969/j.issn.1007-7545.2017.04.002 肖利1，陈玲1，付海阔2，郭权文2 （1.湖南工业大学 冶金与材料工程学院，湖南株洲 412007；2.广东佳纳能源科技有限公司，广东清远 513000） 摘要：采用酸析法结晶钴铜矿浸出反萃液中硫酸铜。结果表明，沉淀3 h，结晶率可达第一个最大值80%左右，沉淀5 h，结晶率下降至70%左右，此后随着反应时间的增加，结晶率增加；结晶过程随着溶液温度的降低，结晶率上升；结晶过程随着硫酸用量的增加，结晶率先升高后降低；结晶过程随着铜反萃液中Cu2+浓度的增加，结晶率增加。最佳工艺条件为：室温、每100 mL铜反萃液中加入30 mL硫酸、沉淀3 h，结晶率超过80%。结晶母液可循环利用，不会带来环境污染。 关键词：酸析法；反萃液；硫酸铜；结晶 中图分类号：TF111.34 文献标志码：A 文章编号：1007-7545（2017）04-0000-00 Acid-Precipitation Crystallization of Copper Sulfate from Extraction Solution of Lixivium of Copper-Cobalt Ore XIAO Li1, CHEN Ling1, FU Hai-kuo2, GUO Quan-wen2 (1. School of Metallurgical Material Engineering, Hunan University of Technology, Zhuzhou 412007, Hunan, China; 2. Guangdong Jiana Energy Technology Company, Qingyuan 513000, Guangdong, China) Abstract：CuSO4·5H2O crystal was prepared from extraction solution of leaching copper-cobalt ore by acid-precipitation method. The results show that crystallization rate of CuSO4·5H2O reaches first peak value about 80% in three hours and then drops to about 70% in five hours, and crystallization rate rises with increase of reaction time after 5 h. Crystallization rate rises with drops of solution temperature during crystallization. Crystallization rate first rises and then drops with increase of dosage of sulfuric acid. Crystallization rate rises with increase of Cu2+ concentration in copper strip liquor. Crystallization rate is 80% above under the optimum conditions including room temperature, sulfuric acid dosage of 30 mL for 100 mL copper extraction solution, and precipitation time of 3 h. Recycled solution after crystallization of copper sulfate can be cyclic utilized without environment pollution. Key words：acid-precipitation method; extraction solution; CuSO4·5H2O; crystallization 硫酸铜是非常重要的化工产品，在电镀、印染、颜料、农药等方面广泛应用。工业生产中常由铜矿湿法冶炼制备硫酸铜，而铜矿资源中伴生铜是非常重要的组成部分[1-2]。因此，研究伴生铜矿提取和制备化工产品是铜矿资源开发利用热点之一，具有长远的经济价值[3-9]。钴铜矿作为湿法提取钴的重要资源，含铜量较高，在提取钴的同时综合回收利用铜资源，一方面避免了重金属离子带来的环境危害，另