湿式过氧化物氧化法处理硫化钠废碱液的动力学研究-高校化学工程学报.PDF

19 2 No.2 Vol.19 2005 4 Journal of Chemical Engineering of Chinese Universities Apr. 2005 1003-9015(2005)02-0268-05 , , , (, 266042) (Fenton ) (CWPO) CWPO 120 99% , Fe2+ pH CWPO dC 0.979 − 26.1095exp(=−29353/ RT )[H O ] C 2 2 0 dt Fenton X703.1 X783 A Study on the Kinetics of Wet Peroxide Oxidation of Sodium Sulfide Containing Wastewater TIAN Jin-jun, YE Qing-guo, KONG De-liang, DING Ke (College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042 China) Abstract Sulfides usually will inhibit the waste water biodegradation and sometimes pretreatment is needed to get rid of it. Here the catalytic wet peroxide oxidation(CWPO) process was proposed to pretreat the sulfides. The effect of CWPO on the removal of sodium sulfide in the west water was experimentally studied and the oxidation kinetics of the sulfide removal was investigated. The results show that the sodium sulfide removing rate of 99% can be reached in 120 minutes, and the oxidation reaction is a first-order reaction. The concentration of Fe2+ and the pH value have little effect on the reaction rate, and the amount of H O used is 2 2 the chief factor affecting the oxidation reaction. The kinetic equation for the oxidation reaction of sodium sulfide was establi