液相色谱法分析卷烟主流烟气中的挥发醛-烟草科技.PDF

/ Tobacco Science Technology/Tobacco Chemistry 2003 10 ( 195 ) , 　 (重庆烟草工业公司技术中心, 重庆市南岸区南坪东路2 号　400060) :HPLC;醛类化合物;卷烟;烟气 :为了快速 确地分析卷烟主流烟气中的低级醛酮类化合物, 建立了通过装有 2, 4-二硝基苯 肼(DNPH)衍生化试剂酸性溶液的装置捕集烟气, 以吡啶为稳定剂, 采用配有二极管阵列检测器的高效 液相色谱仪测定卷烟主流烟气中的挥发性醛酮类化合物的方法。该方法的C 5%, 回收率95%, 并 用外标法定量测定了7 种牌号卷烟主流烟气中的5 种醛酮类化合物。该方法操作简便、快速、重复性 好、回收率高, 适用于卷烟烟气中的醛类化合物的分析。 :TS411.2　:A　:1002-0861(2003)10-0022-04 Analysis of Volatile Aldehydes and Ketones in Mainstream Cigarette Smoke with HPLC ZHU LI-JUN and DAI YA Technology Center of Chongqing Tobacco Industrial Co., Ltd., Chongqing 400060, China Keywords:HPLC;Cigarette; olatile aldehyde;Mainstream smoke Abstract:In order to determine low aldehydes and ketones in mainstream cigarette smoke rapidly and accurately, a method was developed by trapping cigarette smoke with an acidic solution of 2, 4-Dinitrophenylhydrazine, a deriving agent, using pyridine as a stabilizer, and determining the low molecular weight volatile aldehydes and ketones in samples by high performance liquid chromatography with a diode array detector.The C of this method was below 5%and the average recovery of volatile aldehydes and ketoneswas over 95%.The five compounds, formaldehyde, acetaldehyde, acrolein, acetone and propylaldehyde, in the mainstream smoke of seven brands of cigarettes were determined by an external standard method.This method was simpler, faster and suitablefor analysisof low aldehy- des and ketones in mainstream cigarette smoke. 　　 , , , , (HPLC) [1, 2] 。 。, HPLC , , 。, 、、 , , , 。 。 [3, 4]