金属碳纳米复合材料的制备及其生物传感性能研究-化学工程与技术专业论文.docxVIP

万方数据 万方数据 (3)通过对纳米碳管多巴胺功能化修饰，得到 Ag NPs/PDA/CNTs 的复合材料， 具有非常好的抗菌性能。浓度为 50 μg/mL 的 Ag NPs/PDA/CNTs 对大肠杆菌(E. coil)的灭菌率为 100%，6.25 μg/mL 的 Ag NPs/PDA/CNTs 仍有 93.8%的灭菌率； 浓度为 6.25 μg/mL 的 Ag NPs/PDA/CNTs 对金黄色葡萄球菌(S. aureus)的灭菌率为 100%，2 μg/mL 的 Ag NPs/PDA/CNTs 仍有 93.1%的灭菌率。 (4)通过制备不同形貌的金纳米颗粒，考察形貌对其在近红外光激发下光热性 质的影响。选取光热性质最优异的金纳米星(gold nanostars，GNs)与纳米碳管 (MWCNTs)复合，利用两种材料的协同作用提高复合材料的光热性质。在 808nm、 功率密度为 1W/cm2 的激光光源下照射 5 min，GNs 升温 43.6℃。MWCNTs/GNs 复合材料的光热效应比 GNs 更为明显。 关键词：纳米碳材料；金属纳米颗粒；葡糖糖传感器；过氧化氢传感器；无酶 传感器 II Abstract Small biomecular are essential for living beings. Chemical and biological sensors that can record the level of small biomecular with real-time and dynamic monitoring have been intensively explored recently. For example, glucose sensors are crucial for the effective treatment of diabetics, who can test physiological blood glucose levels frequently with a glucose sensor to avoid diabetic emergencies. Hydrogen peroxide is a metabolic intermediate. The accumulation of hydrogen peroxide can produce reactive oxygen species that will result in oxidative stress such as DNA damage. Monitoring of hydrogen peroxide level is of great importance for biomedical science. Glucose sensors and hydrogen peroxide sensors based on enzymatic methods have been extensively investigated. However, the enzymatic sensors usually suffer from limited lifetime and are sensitive to light, heat, pH value and chemcals. Thus, it is imperative to develop nonenzymatic sensors to figure out these problems. Nanostructured metal or metal oxides have been employed to develop nonenzymatic sensors due to their advantages such as simplicity, sensitivity, selectivity, and cost-effective. Moreover, the high surface-to-volume ratio of these nanostructures shows enhanced electrocatalytic response to the target molecular. Herein, we developed nonenzymatic glucose and hydrogen peroxide sensors based on metal/carbon composite nanomaterials, as described belo