冻融作用对土壤胶体及胶体结合态铅迁移的影响.PDF

冻融作用对土壤胶体及胶体结合态铅迁移的影响.PDF

2019,38(2):342-347 农 业 环 境 科 学 学 报 2019年2月 JournalofAgro⁃EnvironmentScience 王 展,邹洪涛,范庆锋,等.冻融作用对土壤胶体及胶体结合态铅迁移的影响[J].农业环境科学学报,2019,38(2):342-347. WANGZhan,ZOUHong-tao,FANQing-feng,etal.Effectoffreezing/thawingontransportofsoilcolloidsandcolloidallead[J].JournalofAgro-Environment Science,2019,38(2):342-347. 冻融作用对土壤胶体及胶体结合态铅迁移的影响 王 展,邹洪涛,范庆锋,岑佳蓉,张玉龙* (沈阳农业大学土地与环境学院,沈阳 110866) 摘 要:以东北地区棕壤为研究对象,通过人工控温和土柱淋洗试验,研究了不同冻融处理下铅污染土柱中土壤胶体和胶体结合 态铅的迁移特征。结果表明:土壤高含水量(田间持水量100%)条件下冻融作用促进土壤胶体的迁移;土壤低含水量(田间持水量 10%)条件下冻融作用对土壤胶体的影响减弱。淋洗试验中,土壤胶体在前20min内大量淋失出土体,随后淋失量急剧减少;且前 20min内的土壤胶体淋失量随着冻融次数的增加先增加后减少。污染土柱中铅主要以胶体结合态的形式迁移,其迁移特征和受 冻融作用影响的趋势与土壤胶体类似。冻融处理后滞留在土柱深层的铅含量较高,表明冻融作用能够促进铅向深层土壤迁移。 关键词:冻融;土壤胶体;胶体结合态铅;迁移 中图分类号:X53 文献标志码:A 文章编号:1672-2043(2019)02-0342-06 doi:10.11654/jaes.2018-0444 Effectoffreezing/thawingontransportofsoilcolloidsandcolloidallead WANGZhan,ZOUHong-tao,FANQing-feng,CENJia-rong,ZHANGYu-long* (CollegeofLandandEnvironment,ShenyangAgriculturalUniversity,Shenyang 110866,China) Abstract:Transportcharacteristicsofsoilcolloidsandcolloidallead(Pb)incontaminatedsoilcolumnstreatedwithdifferentfreeze/thawing cycleswereinvestigatedbysimulatingthetemperatureconditionsinsoilcolumnleachingexperiments.Brownsoilsampleswerecollected fromthenortheastofChina.Theresultsshowedthatfreezing/thawingacceleratedthetransportofsoilcolloidsunderhighersoilwatercon⁃ tents(100%offieldcapacity)anddecreaseditunderlowersoilwatercontents(10%offieldcapacity).Aconsiderableproportionofsoilcol⁃ loidsleachedoutduringthefirst20mininthecolumnleachingexperiment,afterwhichtimetheleachingamountdecreasedsharply.More⁃ over,theamountofsoilcolloidsleachedduringthefirst 20 minincreasedfirstandthendecreasedwiththeextensioninfreezing/thawing time.PbpresentinthecontaminatedsoilcolumnswastransportedmainlyintheformofcolloidalPbanditstransportcharacteristicswere

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