毕业co2dme混合体系跨临界吸收式动力循环热转换机理.docxVIP

co2+dme混合体系跨临界吸收式动力循环热转换机理 摘要 本文以co24DME r元体系作为吸收式动力循环的潜力工质对。引入“化学热机”概念，用子循 环划分的方法将整个循环分为化学热机子循环和热机子循环。基于循环系统的操作压力和与热源的兀 配稈度，对比分析了 CO.+DME体系跨临界操作条件优于亚临界和超临界条件的本质原因。建立了一 套典型的CO2+DME跨临界吸收式动力循环模拟模型。基于文献报道的气液相平衡数据，选择PR方 程作为物性计算模型，分别计算了循环物流的组成、流率、焰值利嫡值。根据循环系统的Qs和lgpj 图，分别分析了两个子循环Z间的耦合关系与能呈转换。从分析结果可以看出，由于耦合了化学热机, 不仅实现了对能量的梯级利用，同时进一步降低了透平出口圧力，热转功过程得到强化，使得热机子 循环热转功效率由14.06%提升到15.79%。最后，采用参数分析法，探索了不同吸收温度(25,30,35和 40°C)下，化学热机子循环高压端压力对整个循坏热转功效率的影响。结果表明，降低化学热机子循 环运行压力是循环优化的一个方向，有助于提高对能量的二次利用率。 关键词吸收式动力循环；化学热机；能乗梯级利用；热转功效率；CO2+DME Heat Conversion Mechanism forCO2+Dimethyl Ether Absorption PowerTrans-critical Cycle FENG Le-jun, ZHENG Dan-xing, SHI Lin* (Tsinghua University, Haidian District Beijing 100084. China) (Tel: 010 Email: HYPERLINK mailto:mxsl@mail.tsinghua.cdu.cn mxsl@mail.tsinghua.cdu.cn) Abstract CO2+DME binary system was considered to be the working fluid of absorption power cycle in this work. The “Chemical heat engine concept was introduced, and divided the cycle into two sub-cycles: Chemical heat engine sub-cycle and Heat engine sub-cycle? Then comparatively analyzed the essential reason of trans-critical operation condition was better than sub-critical and supercritical based on the operation pressure and the degree of match the heat source? An absoiption power cycle simulation program was established, and the PR equation was selected as the calculation model. Then the composition, flow rate, enthalpy value and entropy value of the cycle streams were calculated respectively. According to the T-s and Ig p?h diagrams of the cycle, the coupling relationship and heat conversion mechanism of the two sub-cycles were analyzed. As the result shows, due to the coupling of Chemical heat engine sub-cycle, the heat achieved 基金项目：国家口然科学基金重点项目(Grant No,国家重点硏发计划(Grant No. 2016YFB0901405)国家口然科学棊金创新研究群体(Grant No gradient utilization and the turbine outlet pressure has reduced, and the heat conversion work efficiency of Heat engine was improved fi