含二级供电基团的三苯胺类光敏染料合成及太阳能电池中的应用.PDF

2011 年第69 卷 化 学 学 报 Vol. 69, 2011 第18 期, 2092～2098 ACTA CHIMICA SINICA No. 18, 2092～2098 ·研究论文· 含二级供电基团的三苯胺类光敏染料合成及太阳能电池中的应用 梁 茂 徐英军 王旭达 刘秀杰 孙 喆 薛 松* (天津理工大学化学化工学院 天津 300384) 摘要 以N,N-二甲基苯胺作为二级给电子单元, 合成两种具有不同长度共轭链的三苯胺类光敏染料XS19 和XS22. 研 究了它们的光物理与光电化学性质, 并将它们用作 TiO2 纳米晶电极的光敏化剂引入太阳电池, 结果表明, N,N-二甲基 苯胺的引入能够抑制染料敏化太阳能电池中的电子复合, 提高电池的光电转换效率. XS22 表现出更好的光伏性能, 在 AM1.5 (100 mW•cm－2) 的光强下, XS22 敏化电池的开路电压( V )为685 mV, 短路电流密度(J )为9.6 mA•cm－2, 填充 OC SC 因子(FF)为0.72, 总光电转换效率为4.7%. 关键词 染料敏化太阳能电池; 有机染料; 光电转换效率; 电子复合 Synthesis of Triarylamine Dyes Containing Secondary Electron-dona- ting Groups and Application in the Dye-sensitized Solar Cells Liang, Mao Xu, Yingjun Wang, Xuda Liu, Xiujie Sun, Zhe Xue, Song* (College of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384) Abstract Two triphenylamine based dyes (XS19 and XS22) containing N,N-dimethylaniline unit as sec- ondary electron-donating groups with different conjugated lengths were synthesized and characterized with regard to their photophysical and photoelectrochemical properties. The dyes were applied into nanocrystal- line TiO2 dye-sensitized solar cells through standard operations. It was found that, introduction of N,N-dimethylaniline unit suppressed dye aggregation and brought about superior performance over the sim- ple triphenylamine dye in