百色不同功能区土壤重金属形态分布及其生态风险评价-广东农业科学.PDF

广东农业科学 2013 年第 11 期 165 百色不同功能区土壤重金属形态分布及其生态风险评 黄科瑞 刘 芳 张金磊 陈华妮 黎远成 百色学院化学与生命科学系袁 广西 百色 533000 冤 摘 要 在百色城区及周边县城选择城市中心区尧矿区和工业区采集土壤袁分析其重金属元素 As尧Cd尧Cr尧Cu尧Mn尧Ni尧Pb 和 Zn冤的含量及存在形态遥 结果表明袁城市中心区土壤的重金属含量处于无污染水平袁属于轻微生态危害程度曰而工业区和矿区土壤 的重金属含量超出百色土壤背景值袁污染较严重袁属于极强生态危害程度袁其中 Cd 对土壤 RI 的贡献最大遥不同功能区土壤重金属 的分布形态特征既有相似性 有差异性遥 城市中心区尧工业区与矿区土壤中袁Cd 的可交换态含量较高袁占总量的 18.2%~29.5% 曰Mn 则主要以铁-锰氧化物结合态和残余态的形式存在曰其余重金属元素 As尧Cr尧Cu尧Ni尧Pb尧Zn冤以残余态为主袁占总量的 70%以上遥 关键词 不同功能区曰 重金属曰 形态分布 中 分类号 X825 文献标识码 A 文章编号 1004-874X 2013冤11-0165-04 Speciation and ecological risk assessment of heavy metal in soils from different functional zones of Baise city HUANG Ke-rui, LIU Fang, ZHANG J in-lei, CHEN Hua-ni, LI Y uan-cheng (De partment of Chemistry and Life Scie nce , Baise Univ ersity, Baise 533000, China) Abstract: The content and speciation of heavy metal (As, Cd, Cr, Cu, Mn, Ni, Pb and Zn) in soils from different functional zones (mineral, industrial and urban central zone) of Baise city were investigated. The results indicated that heavy metal content in soil from urban central zone was at clean level, and the potential ecological risk was slight. However, heavy metal content in soils from mining and industrial zone exceeded the soil background of Baise and the soils have been polluted seriously. The assessment of potential ecological risk revealed that heavy metal in soils from mineral and industrial zones possessed very high potential ecological risk and the potential