Rb2O-V2O5体系热力学优化-中国科技论文在线.PDFVIP

中国科技论文在线 Rb O-V O 体系热力学优化 2 2 5 李艺，谢伟，曹战民** 5 摘要 ： Rb O-V O 体系相图、热力学数据以及晶体结构数据进行综述与评估，解决 2 2 5 了已有相图实验数据之间关于“X”相是否存在的矛盾，获得了可靠的实验数据。采用阴、 阳离子贡献方法对中间化合物RbV O RbVO Rb V O Rb V O 和Rb VO 298 K 3 8 3 32 18 61 4 2 7 3 4 生成焓（元素参考态）和标准熵进行估算。通过对Rb2O-V2O5体系的液相及中间化合物建立 热力学模型，利用相图计算技术进行热力学优化，很好的重现了相图和热力学实验数据，最 10 终获得一套合理、可靠、自洽的模型参数。 关键词：Rb O-V O 相图；热力学；热力学模型 2 2 5 中图分类号：O642.4 Thermodynamic Optimization of Rb O-V O System 2 2 5 15 LI Yi, XIE Wei, CAO ZhanMin (School of Metallurgy and Ecological Engineering,University of Science and Technology Beijing) Abstract: In this paper,the Rb O-V O system phase diagram ，thermodynamic data and crystal 2 2 5 structure data were reviewed and evaluated. The contradiction between the existing phase diagram experimental data about X phase is solved.The enthalpy of formation (element reference) and 20 standard entropy of 298 K for RbV O , RbVO , Rb V O , Rb V O and Rb3VO4 were estimated by