高分子专业英语UNIT 10.pptxVIP

UNIT 10; Tb——脆化温度 Tg——玻璃化温度 Tf——黏流温度 Td——分解温度;第一段 An ordinary rubber? ball if?cooled?below -70 ℃ becomes so hard and brittle(易碎的） that it will break into pieces like a glass ball falling on a hard surface! 设想一个普通的橡胶球在零下70摄氏度冷却会变得如此硬而脆以至于像一个玻璃球摔碎在坚硬的表面成碎片。 Why does a rubber ball become like glass below -70℃? ;This is because there is a “temperature boundary（范围）” for almost all amorphous（无定形的） polymers (and many crystalline polymers结晶聚合物) only above which the substance remains soft,flexible(柔软的） and rubbery（橡胶状的） and below which it becomes hard,brittle and glassy. 这是因为对于几乎所有的无定