双溶剂协同萃取精馏分离乙酸甲酯-甲醇-水工艺模拟-Chin.J.Process.PDFVIP

第 17 卷第 2 期 过 程 工 程 学 报 Vol.17 No.2 2017 年 4 月 The Chinese Journal of Process Engineering Apr. 2017 反应与分离 双溶剂协同萃取精馏分离乙酸甲酯甲醇水工艺模拟 * 高晓新， 朱碧云， 顾 强， 蒋 宇， 杨德明 (常州大学石油化工学院，江苏 常州 213164) 摘 要：针对乙酸甲酯甲醇水体系，在筛选萃取剂的基础上，提出了双溶剂四塔萃取精馏、单溶剂三塔萃取精馏及双溶剂协 同萃取精馏3 种分离工艺. 用 Aspen Plus 软件模拟萃取精馏过程，并以能耗和年总费用作为评价指标，用 SRPolar 方程计算各 萃取精馏工艺合适的操作参数和设备参数. 结果表明，水和乙二醇是分离该体系较合适的萃取剂，单溶剂三塔萃取精馏工艺较 双溶剂四塔萃取精馏工艺优异，能耗减少约 37.9%，年总费用降低约 38.9%. 双溶剂协同萃取精馏工艺比双溶剂四塔萃取精馏工 艺和单溶剂三塔萃取精馏工艺能耗分别减少约 45.6%和 12.4%，年总费用分别降低约43.5%和 11.6%. 关键词：乙酸甲酯甲醇水体系；双溶剂；协同萃取精馏；能耗；费用 中图分类号：TQ021.8 文献标识码：A 文章编号：1009606X(2017)02025405 DOI: 10.12034/j.issn.1009-606X.216232 Process Simulation for Separation of Methyl AcetateMethanolWater by Double Solvent Synergistic Extractive Distillation GAO Xiao-xin, ZHU Bi-yun, GU Qiang, JIANG Yu, YANG De-ming* (College of Petrochemical Engineering, Changzhou University, Changzhou, Jiangsu 213164, China) Abstract: According to the characteristic of methyl acetatemethanolwater system in the presence of two kinds of azeotrope, three separation processes such as double solvent four column extractive distillation process, single solvent three column extractive distillation process and double solvent synergistic extractive distillation process were proposed on the basis of screening the extraction agent for the system. Energy consumption and total annual cost (TAC) as evaluation index, the simulations for the three separation processes were performed by Aspen Plus software which SRPolar thermodynamic model was used to calculate