氧化乐果的振动光谱及其表面增强拉曼散射研究-分析化学.PDFVIP

38 ( FENXIHUAXUE) 8 2010 8 Ch inese Journal ofAnalytical Chem istry 1127~ 1132 DOI: 10. 3724 / SP. J. 1096. 2010. 01127 * 1 1 2 2 1 吉芳英 黎司 虞丹尼 周光明 何 强 1 (, , 400030) 2 (, 400715) ATR-FT IRFT-, ; /-, ( SERS), , SERS ; : M (NH), M (CH ) , Am ide Ñ, M( O C ), M( O ) , M(C-S); as as 3 , 2. 0@ 10- 2 m ol/L SERS, , 2. 0@ 10- 10 mol/L , SERS ; , , ; -FT-; FT-; ; 1 , O, O--S-(N-), [ 1, 2] , , 1 [ 3, 4] , , , , [ 4~ 6] [ 5, 7] [ 1, 8] [ 9] GC H LC [ 2] , , , [ 10] , , , , , , [ 11] , (ATR)- KBr [ 12] , , ( SERS) , [ 13~ 15] ATR-FTIRFT- [ 16] , /- , SERS SERS, , SERS, 2 2. 1 - 1 RFS 100/S FT- ( Bruker), 60 mW, 80 , 4 cm ; - 1 - 1 IR restige-21 FT-( Shmadzu), 3600. 0~ 600. 0 cm 40 , 4 cm ; HART ( IKE Technologies, ), ZnSe, 45b, 2. 4, - 1 4000~ 600 cm (, Dr. Ehrenstorfer), ; AgNO 3