3 纯流体热力学性质(Part B).ppt

The saturated pressure of 1-butene liquid at 273.15K is determined by the following method: For normal point, Tn=267 K, psat=1.0133 bar; for critical point, Tc=419.6 K, pc=40.2 bar. Therefore we can obtain the solution of A and B as A = 10.126 B = 2699.11 Then we calculate the saturated pressure of 1-butene liquid at 273.15 K as psat=1.2771 bar. (p1=1.27 bar) Step 1: Vaporization of saturated 1-butene liquid at 273.15K △H lv is the latent heat of vaporization(蒸发潜热). The latent heat of vaporization at normal point is calculated by the following Riedel equation With Tn = 267 K, Tr,n= 267/419.6 = 0.636, and pc = 4.02 MPa, the calculation result is . The vaporization of saturated liquid is an reversible process. The latent heat of vaporization at 273.15 K is estimated using the following equation With Tr =273.15/420=0.65, the calculation result is Step 2: The transformation of saturated 1-butene vapor into an ideal gas at the initial conditions of T1=273.15 K and p1=1.2771 bar. Due to the EOS of saturated 1-butene vapor at T1 = 273.15K and p1 = 1.277 bar is not known, we should use the Pitzer generalized methods to calculate the residual properties. Tr,1 = 0.651, pr,1 = 0.0361 Since the pressure is relatively low, we can use the generalized Pitzer Correlations for the second virial coefficient to evaluate Step 3: Changes in the ideal-gas state from (273.15 K, 1.2771 bar) to (473.15 K, 70 bar). Step 4: Transformation of 1-butene from the ideal gas into vapor at the state of T2=473.15 K and p2=70 bar. Also due to the EOS of 1-butene vapor at T1 = 473.15 K and P2 = 70 bar is not known, we should use the Pitzer generalized methods to calculate the residual properties. Tr,2 = 1.13, Pr,2 = 1.74 we should use the generalized Pitzer Correlations for the compressibility factor to evaluate Since , From Figs 3-3, 3-5, 3-7 and 3-9, the following results are obtained : Finally, 3.3 逸度和逸度系数 在所有的热力学性质中，Gibbs能是最具有应用价值的一个函数（