聚苯胺包覆酸处理螺旋碳纤维材料的制备和电化学性能-材料研究学报.PDF

第32 卷 第1 期 Vol. 32 No. 1 2018 年1 月 CHINESE JOURNAL OF MATERIALS RESEARCH Jan. 2018 聚苯胺包覆酸处理螺旋碳纤维材料的 制备和电化学性能 史泰龙 唐国霞 赵晨曦 黄新林 刘秀昀 孙益欣 朱亚波 ( 中国矿业大学材料科学与工程学院 徐州 221116) 摘要用原位聚合和乳液聚合两种方法制备聚苯胺(PANI)包覆螺旋碳纤维(CMCs)复合材料，使用红外光谱 (FTIR)，扫描电子显微镜(SEM)，X 射线衍射(XRD)等手段对其形貌和结构进行了表征。结果表明，用硝酸处理 CMCs (表示为H-CMCs)为纤维表面提供含有羧基等含氧官能团。这为苯胺在H-CMCs 表面的聚合提供基础， 有助于PANI 附着在H-CMCs 的表面。用循环伏安、恒流充放电、交流阻抗等电化学方法测试了复合材料的电 化学特性，结果表明：PANI 包覆H-CMCs ，其比电容值明显高于H-CMCs 自身，表现出良好的大电容性能。原 位聚合法更有益于PANI 与H-CMCs 的协同作用，使复合体的电容性能提高。 关键词 复合材料，聚苯胺/碳螺旋纤维复合材料，表征，电容性能 中图分类号 TB321 文章编号 1005-3093(2018)01-0058-07 Preparation and Electrochemical Performance of Composites of Polyaniline Coated Carbon Micro-coils SHI Tailong, TANG Guoxia, ZHAO Chenxi, HUANG Xinlin, LIU Xiuyun, SUN Yixin, ZHU Yabo (School of Materials Science and Engineering,China University of Mining and Technology, Xuzhou 221116, China) Correspondent: ZHU Yabo, Tel: E-mail: zhuyabo@163.com Supported by Foundation of China University of Mining and Technology (No. Manuscript received 2017-02-13, in revised form 2017-09-12 ABSTRACT Composites of polyaniline (PANI)-coated carbon micro-coils (CMCs) were synthesized by in-situ polymerization and emulsion polymerization methods respectively. The morphology and structure of the composites were characterized by FTIR，SEM and XRD. The results show that after CMCs have been treated with nitric acid (H-CMCs), more carboxyl group appeared on their surface, which is benefi- cial to the adhesion of PANI to the surf