功能化离子液体催化酯化反应探究进展.pdfVIP

第47卷第3期 应 用 化 工 Vol.47 No.3 2018年3月 Applied Chemical Industry Mar.2018 功能化离子液体催化酯化反应研究进展 王文治,刘冉,曹萌萌,武宇,吕建平,赵地顺 (河北科技大学 化学与制药工程学院,河北 石家庄 050018) 摘 要:综述了具有不同官能团的单核、双核离子液体催化酯化反应的研究进展,针对不同官能团的单核、双核离 子液体的催化机理、催化效果进行了分析,表明离子液体在酯化反应中的催化活性主要取决于其官能团和阴阳离 子的结构。 通过对比单核、双核离子液体催化酯化反应的研究结果发现,双核离子液体在催化酯化反应性能上相 对于单核离子液体表现出一定的优势。 最后,对离子液体作为酯化反应催化剂的潜在的应用前景进行了展望。 关键词:离子液体;催化;酯化 中图分类号:TQ203.2;TQ225.242;O643.32 文献标识码:A 文章编号:1671-3206(2018)03-0593-06 Research progress of esterification reaction catalyzed by functionalized ionic liquid WANG Wen-zhi,LIURan,CAOMeng-meng,WU Yu,LÜJian-ping,ZHAODi-shun (College of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology,Shijiazhuang050018,China) Abstract:The research progressof esterificationreaction catalyzedby single-core and dual-core ionicliq- uidswithdifferentfunctionalgroupswasreviewed.Andthecatalyticpropertiesandcatalyticmechanismof single-core and dual-core ionic liquidswith different functional groups were analyzed and discussed.The catalytic activity of ionicliquidsinesterificationreactionmainly dependsonthestructureofthefunctional groups,anion and cation.By comparing the research of esterification catalyzed by single-core and dual- core ionicliquids,the dual-core ionicliquidsascatalyst in esterificationreaction showed more advantages than single-core ionicliquids.Finally,thepotential application of ionicliquidsused ascatalystfor the es- terification reaction was prospected. Key words:ionic liquids;catalytic;esterification 酯类化合物在化工行业应用广泛,可用作香料、 子液体催化酯化反应的性能和效果进行了综述。 [1] 增塑剂、溶剂等 。 传统的催化合成酯的方法存在 1 单核离子液体催化