含有机物水溶液电解体系中的阳极材料及其失效特性-中国腐蚀与防护.PDF

第35 卷 第3 期 中国腐蚀与防护学报 Vol.35 No.3 2015 年6 月 Journal of Chinese Society for Corrosion and Protection Jun. 2015 含有机物水溶液电解体系中的阳极材料 及其失效特性 金小寒 胡吉明 张鉴清 浙江大学化学系 杭州 310027 摘要：较详细地介绍了含有机物水溶液电解体系中使用的阳极材料；分析了该种特殊使用环境下阳极的失效 机制，如表面粘污机理与加速溶解机制；综述了提高阳极耐用性的相关对策，包括优化电极组分和阳极再活 化；最后对含有机物水溶液中阳极材料的研究进行了展望。 关键词：阳极 有机物 电解体系 失效机制 中图分类号：TQ 151.4 文献标识码：A 文章编号：1005-4537(2015)03-0199-06 Anode Materials Used in Electrolytic System Containing Organic Compounds and Their Failure Characteristics JIN Xiaohan, HU Jiming, ZHANG Jianqing Department of Chemistry, Zhejiang University, Hangzhou 310027, China Abstract: In this paper, anode materials used for organic compounds containing aqueous electro- lyte were introduced. Further, their failure characteristics were analyzed in terms of surface fouling and accelerated dissolution. Meanwhile, the strategies for failure prevention, including the optimi- zation of chemical composition and anodic re-activation of electrode, were reviewed in details. Fi- nally, the investigation of anode materials in organic compounds containing electrolyte was also prospected. Key words: anode, organic compound, electrolytic system, failure characteristic [1] 功开发了钛基RuO 涂层阳极 ，开创了电化学工业 1 前言 2 电化学工业在国民经济中占有重要地位，电极 的重大变革。查全性先生称这种阳极的开发是“近 [2] 是该工业领域中的核心部件。相对于阴极而言，由 年来电催化研究最辉煌的成就”。由于以Ti 板为 于阳极承受更复杂和苛刻的电解