丙烯酸酯乳液的成膜性能.pdfVIP

2008 24 3 7 化学建材 年 第 卷 第 期 丙烯酸酯乳液的成膜性能 1,2 1 3 吴跃焕 ，赵建青 ，暴志菊 . 5 0640 2. 030008 华南理工大学材料科学与工程学院，广州 ； 太原工业学院应用化学系，太原 ； 3.新华化工有限公司，太原 030008 摘要：通过最低成膜温度和玻璃化温度的测试，系统地考察了粒径、成膜温度、水的塑化作用对丙烯酸酯乳液 成膜性能的影响，并进一步对具有特殊分子形态的寡链聚合物的成膜过程进行了研究。结果表明，乳液的成膜 变形力随粒径的减小而增大；聚合物的亲水性越大，水的塑化作用越强；成膜温度太高，分子链在空间构象上 的物理缠绕程度减小，形成涂膜抵抗外力的能力下降。寡链高聚物由于分子链间的缠结密度较小和具有较高的 构象能，因此成膜变形力大于相互穿透的多分子链聚合物。 关键词：纯丙乳液； 苯丙乳液； 成膜过程； 塑化作用； 寡链聚合物 中图分类号：TQ630.7 文献标识码：A 文章编号：004-672(2008)03-007-05 Film Formation Performance of Acrylate Emulsion / Wu Yue-huan et al // College of Materials Science and Engineering, South China University of Technology Abstract: By tests on minimum film forming temperature and vitrification point, effects of various factors such as particle size, film forming temperature and plastication of water on film formation performance of acrylate emulsion were investigated systematically and further study was carried out of film forming process of pauci-chain polymer with specialty molecular morphology. Testing results showed that deformation force of film formation for emulsion increased with decrease of particle size. The bigger the hydrophilicity of polymer, the stronger the plastication of water. Over high film forming temperature would reduce physical wrap of polymer molecular chain on space conformation, resulting in drop of film capacity against outer force. Owing to low density of molecular chain inter-twist and high conformation energy, film forming deformation force of pauci-chain high polymer was greater than t