冷蒸气原子吸收光谱法测定接装纸中的Hg-烟草科技.PDF

/TobaccoScienceTechnology /TobaccoChemistry 2009 12 ( 269 ) Hg 福建中烟工业公司技术中心,福建省厦门市海沧区新阳工业区新阳路 1 号　361022 :微波消解;冷蒸气;原子 收光谱法;接装纸;Hg :为建立微波消解-冷蒸气原子 收光谱法测定接装纸中 Hg含量的方法, 考察了微波消解、盐酸 (反应介质)浓度、硼氢化钠 (还原剂)浓度和载气流速等测定条件对测定结果的影响,并采用该方法测 定 16 个国产接装纸样品中的 Hg含量。结果表明:①采用 HNO-HC-lHO-HF体系微波消解样品, 3 2 2 样品消解完全;②Hg测定的最佳反应条件为硼氢化钠浓度 0.3%(质量分数),载液中盐酸浓度 5%(体 积分数 ),载气流速为 95 mL/min;③Hg的检出限为0.016 μg/L, 重复性 RSD≤3.0%, 回收率为 90.0% ～98.0%;④16 个接装纸样品中的 Hg含量均低于 0.6 mg/kg, 其中有 2 个样品未检出, 含量为 0 ～ 0.1 mg/kg的样品有 6 个, 含量为0.1 ～0.5 mg/kg的样品有 7 个, 含量为0.599 mg/kg的样品只有 1 个。 :TS411, TS761.2　:B　:1002 -0861 (2009 )12-00 30-04 DeterminationofHginTippingPaperwithColdVaporAtomicAbsorptionSpectrometry LIUXIU-CAI TechnologyCente,rFuianBranchofChinaTobaccoIndustryCorporation, Xiamen361022, Fuian, China Keyword:sMicrowavedigestion;Coldvapo;rAtomicabsorptionspectrometry;Tippingpape;rMercury Abstrac:tAmethodfordeterminingmercury(Hg)intippingpaperwithmicrowavedigestion-coldvapor atomicabsorptionspectrometrywasdeveloped, theinfluencingfactor,s suchasmicrowavedigestion, HCl (reactionmedium)concentration, NaBH(reducingagent)concentrationandcarriergasflowrat,eet.cwere 4 investigated, andthecontentsofHgin16 domestictippingpapersamplesweredeterminedwiththe establishedmethod.Theresultsshowedtha:t1 )thesampleswerecompletelydigestedundermicrowavein HNO-HCl-HO-HFmixturesolution;2 )theoptmiumconditionsfordeterminingHgwere:theHCl 3 2 2 concentrationincarriersolution5%(v/v), NaBH concentration0.3% (m/v)andtheflowrateofcarrier 4 gas95 mL/min;3 )therecoveriesofHgwasfrom90.0% to98.0 % withRSDsof≤ 3.0% andlmiitof detectionof0.0 16 μg/L;4 )theHgcontentinnosamplewashigherthan0.6 mg/kg, in6 sampleswasfrom 0 to0.1 mg/kg, 7 samplesfrom0.1 to0.5 mg/kg, 1 sample0.599 mg/kg, and2 samplesnotdetectable.