原位法制备纳米银修饰碳纳米管环氧导电复合材料-物理化学学报.PDF

物理化学学报(Wuli Huaxue Xuebao) March Acta Phys. -Chim. Sin. 2012, 28 (3), 711-719 711 [Article] doi: 10.3866/PKU.WHXB201112213 原位法制备纳米银修饰碳纳米管环氧导电复合材料 刘孔华 刘 岚* 高 宏 罗远芳 贾德民 (华南理工大学材料科学与工程学院, 广州510640) 摘要: 将碳纳米管(CNTs)和乙酸银同时引入到环氧树脂-咪唑固化体系中, 在固化过程中原位热降解银-咪唑 复合物生成纳米银修饰碳纳米管, 差示扫描量热仪(DSC)表明改性碳纳米管对环氧固化有一定的促进作用. 采 用X-射线衍射(XRD)表征了乙酸银和咪唑配合物[Ag(2E4MZ) ]Ac 的结构, 并提出了原位降解生成纳米银的机 2 理. XRD 结果表明, 单独的乙酸银-咪唑配合物热降解生成的纳米银粒径为21-24 nm, 而配合物在环氧基体中 生成的纳米银粒径为11-13 nm. 添加80%(质量分数)片状微米银粉制备的纳米银/碳纳米管环氧导电复合材料 -5 其体积电阻率低达9×10 Ω·cm. 当纳米银和碳纳米管质量比为80:20 时, 复合材料导电性和剪切强度达到最 佳; 采用扫描电镜(SEM)表征了复合材料的形貌结构. 关键词: 低温烧结; 纳米复合材料; 接触电阻; 导电填料; 体积电阻率 中图分类号: O641.08 In situ Preparation of Epoxy-Based Conductive Nanocomposites Containing Nanosilver-Decorated Carbon Nanotubes LIU Kong-Hua LIU Lan* GAO Hong LUO Yuan-Fang JIA De-Min (College of Material Science and Engineering, South China University of Technology, Guangzhou 510640, P. R. China) Abstract: Nanosilver-decorated carbon nanotubes (CNTs) were prepared by introducing CNTs and silver acetate into an epoxy-imidazole curing system and simultaneous in situ thermal degradation of an Ag-imidazole complex. Differential scanning calorimetry (DSC) results indicated that modified CNTs played a certain role in promoting the curing of the epoxy. The structure of the silver acetate-imidazole complex was characterized by X-ray diffrac