锂离子电池正极材料LiNi04Co02Mn04O2的制备与性能研究梁卫春.doc

doi：10.3969/j.issn.1007-7545.2018.11.012锂离子电池正极材料LiNi0.4 doi：10.3969/j.issn.1007-7545.2018.11.012 梁卫春1，郭欢1，吴理觉1,2，靖青秀3 (1.广东佳纳能源科技有限公司，广东 清远 511500； 2.清远佳致新材料研究院有限公司，广东 清远 511500； 3.江西理工大学，江西 赣州 341000) 摘要：以自制Ni0.4Co0.2Mn0.4(OH)2前驱体和Li2CO3为原料，在空气气氛下采用固相烧结工艺制备了LiNi0.4Co0.2Mn0.4O2锂离子电池正极材料。通过SEM和XRD等手段对材料烧结前后形貌与结构进行表征，并测试了烧结后锂离子电池正极材料的电化学性能。结果表明，Ni0.4Co0.2Mn0.4(OH)2前驱体具有良好的片状嵌入结构，且烧结制备的LiNi0.4Co0.2Mn0.4O2正极材料混排因子c/a=4.967 3，阳离子混排因子I(003)/I(104)=1.25、I(006+102)/I(101)=0.333、I(018)/I(110)=0.87，表明LiNi0.4Co0.2Mn0.4O2具有良好的层状结构。在2.5~4.6 V、0.2C和0.5C下，LiNi0.4Co0.2Mn0.4O2正极材料的首次放电比容量分别为166和154 mAh/g，循环80次后容量分别保持为111和100 mAh/g，具有良好的电化学性能。 关键词：锂离子电池；正极材料；LiNi0.4Co0.2Mn0.4O2；性能 中图分类号：TM912.9 文献标志码：A 文章编号：1007-7545（2018）11-0000-00 Synthesis and Performance Study of LiNi0.4Co0.2Mn0.4O2 Cathode Material for Lithium-ion Batteries LIANG Wei-chun1, GUO Huan1, WU Li-jue1,2, JING Qing-xiu3 (1. Guangdong Jiana Energy Technology Co., Ltd., Qingyuan 511500, Guangdong, China; 2. Qingyuan Jiazhi New Materials Research Institute Co., Ltd., Qingyuan 511500, Guangdong, China; 3. Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China) Abstract：LiNi0.4Co0.2Mn0.4O2 cathode material for Li-ion batteries was synthesized by sintering process with Ni0.4Co0.2Mn0.4(OH)2 precursor and Li2CO3 as raw materials in air atmosphere. Morphology and crystal structure were evaluated by SEM and XRD before and after sintering Ni0.4Co0.2Mn0.4(OH)2 precursor with Li2CO3. Electrochemical properties of LiNi0.4Co0.2Mn0.4O2 cathode material were tested. The results show that primary particles of Ni0.4Co0.2Mn0.4(OH)2 precursor are of obvious layered structure. Cathode material LiNi0.4Co0.2Mn0.4O2 has obvious hexagonal layered type structure with low cation mixing factor of c/a=4.967 3, ratio of characteristic peaks I(003)/I(104)=1.25, I(006+102)/I(101)=0.333, and I(018)/I(110)=0.87. The initial discharge capacity of LiNi0.4Co0.2Mn0.4O2 is 166 and 154 mAh/g respectively in the voltage range