电厂机组流动加速腐蚀研究进展及防护措施-腐蚀科学与防护技术.PDF

第30 卷 第5 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol. 30 No. 5 2018 年9 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Sep. 2018 电厂机组流动加速腐蚀研究进展及防护措施 林 彤 周克毅 司晓东 东南大学能源与环境学院 南京 210096 摘要 流动加速腐蚀(FAC) 已成为电厂机组第二大失效方式，严重影响机组的安全运行。本文从FAC 的机理 出发，对影响FAC 速率的流体动力学、环境和材料三方面因素分别进行论述，分析了造成流动加速腐蚀的内在 原因，通过合理的管道设计、材料选择和水化学控制可以有效地提高管道抵抗FAC 的能力，减小电厂发生FAC 造成管道泄漏的可能性，提高电厂的安全性和可靠性，对火电机组和核电站避免流动加速腐蚀具有指导意义。 关键词 流动加速腐蚀 氧化膜 传质系数 溶解度 中图分类号 TG 174 文章编号 1002-6495(2018)05-0543-09 Research Progress on Flow-accelerated Corrosion of Power Plant and Contermeasures LIN Tong, ZHOU Keyi, SI Xiaodong School of Energy and Environment, Southeast University, Nanjing 210096, China Correspondent: ZHOU Keyi, E-mail: boiler@seu.edu.cn Supported by National Natural Science Foundation of China and Postgraduate Research Practice Innovation Program of Jiangsu Province (KYCX 17_0075) Manuscript received 2017-12-18, in revised form 2017-12-25 ABSTRACT Flow-accelerated corrosion (FAC) has become the second largest failure mode for power plant facilities, which seriously affects the safe operation of the power unit. Therefore, the effect of envi- ronmental- and material-factors on the FAC rate is discussed in terms of the relevant FAC mechanism and the hydrodynamics in this paper. It follows that after correct diagnose for the cause of FAC, to en- hance the resistance to FAC of the pipeline effectively through reasonable design, proper material selec- tion and appropriate chemical control of water, as