基于横向分子间氢键的棒-线型分子自组装研究进展RecentProgress.PDFVIP

2009 年第 29 卷 有 机 化 学 Vol. 29, 2009 第 4 期, 528～535 Chinese Journal of Organic Chemistry No. 4, 528～535 ·综述与进展· 基于横向分子间氢键的棒-线型分子自组装研究进展 张小兵 a,b 李 敏*,b (a 河南理工大学瓦斯地质研究所 焦作 454003) (b 吉林大学材料科学与工程学院 长春 130012) 摘要 棒-线(Rod-Coil)型分子的合成及其自组装行为研究是当前超分子材料研究领域的重要研究方向. 与传统的柔性 (Coil-Coil)型嵌段聚合物和 Rod-Coil 型嵌段聚合物相比, Rod-Coil 型分子表现出不同的相行为、自组织特性和微结构, 可以自组装形成多种纳米结构. 研究结果显示, 横向分子间氢键是 Rod-Coil 型分子自组装形成液晶相和(或)有机凝胶 等自组装体的主要驱动力. 主要介绍目前文献报道的横向分子间氢键驱动下 Rod-Coil 型分子自组装. 关键词 棒-线型分子; 自组装; 氢键 Recent Progress in Rod-Coil Molecules by Self-Assembly via Lateral Intermolecular H-bonding Zhang, Xiaobinga,b Li, Min*,b a ( Institute of Gas-geology, Henan Polytechnic University, Jiaozuo 454003) (b Department of Materials Science and Engineering, Jilin University, Changchun 130012) Abstract Self-assembly of rod-coil molecules is an important research interest in supramolecular materials science realms. Compared to the traditional flexible coil-coil and rod-coil block polymers, rod-coil mole- cules exhibit very different phase behavior, self-assembling characters and microstructures. And correlative investigations showed that the rod-coil molecules could come into being several nanostructures, such as mushroom-like nature, smectic phase, cubic phase, hexagonal columnar phase, and so on. The studies con- firmed that the intermolecular H-bonding interacti