毕业论文-Fenton试剂氧化处理印染废水研究.docVIP

Fenton试剂氧化处理印染废水研究 PAGE 10 本科毕业设计 环境工程 Fenton试剂氧化处理印染废水研究 Study on the treatment of dyeing wastewater by UV-Fenton and ferrioxalate / H2O2 / Solar light oxidation processes Fenton试剂氧化处理印染废水研究 PAGE 11 Fenton试剂氧化处理印染废水研究 摘要：采用UV-Fenton催化氧化和日光/H2O2/草酸铁络合物催化氧化两种高级氧化法处理印染废水。通过实验研究了pH、FeSO4·7H2O和H2O2的投加量、反应时间、紫外线催化对UV-Fenton催化氧化法脱色和COD去除率的影响。对于日光/H2O2/草酸铁络合物催化氧化法，主要研究了投加方法、Fe3+、草酸钠和H2O2的投加量以及pH、反应时间等对染料脱色的影响。结果表明：UV-Fenton催化氧化法确定的最佳条件为：0.1mol/L FeSO4·7H2O溶液的投加量为1mL，30% H2O2的投加量为2mL，pH为3，反应时间为3h；日光/H2O2/草酸铁络合物催化氧化确定的最佳条件为：1g/L硫酸铁投加量为1mL，30% H2O2的投加量为0.5ml，1.8g/L草酸钠溶液投加量为0.4mL，pH为3~4。 关键词：印染废水；UV-Fenton；催化氧化；太阳光；草酸铁络合物 Study on the treatment of dyeing wastewater by UV-Fenton and ferrioxalate / H2O2 / Solar light oxidation processes Abstract?: The effects of main factors of UV-Fenton and ferrioxalate/ H2O2/solar light processes on dyeing wastewater treatment efficiency have been studied. To UV-Fenton, Parameters such as pH, the dosage of FeSO4·7H2O or H2O2,treatment time, the function of UV light and the like are investigated in terms of the removal rates of chromaticity and COD. To ferrioxalate/ H2O2/solar light process, Parameters such as the ways of feeding, the dosage of ferrioxalate or H2O2, pH, treatment time and the like are investigated in terms of the removal rates of chromaticity. The results show that to UV-Fenton，the best reaction conditions are：the dosage of FeSO4·7H2O is 1mL，the dosage of H2O2 is 2mL，pH 3，treatment time is 3 hours；To ferrioxalate/ H2O2/solar light process，the best reaction conditions are：the dosage of ferrioxalate is 1 mL，the dosage of H2O2 is 0.5 mL，pH,3~4。 Key words：dyeing wastewater；UV-Fenton；catalytic oxidation；solar light；ferrioxalate 目　录 TOC \o 1-4 \h \z \u HYPERLINK \l _Toc293614015 1 引言 PAGEREF _Toc293614015 \h 1 HYPERLINK \l _Toc293614016 2 材料与方法 PAGEREF _Toc293614016 \h 3 HYPERLINK \l _Toc293614017 2.1 UV-Fenton催化氧化法 PAGEREF _Toc293614017 \h 3 HYPERLINK \l _Toc293614018 2.1.1 实验原理 PAGEREF _Toc293614018 \