固相剪切碾磨法制备石墨PVC抗静电复合材料-应用化学专业论文.docxVIP

Title : Preparation of PVC/ graphite flame retardant and antistatic Composite materials by Solid State Shear Milling (S3M) Method Discipline : Applied chemistry Author : Zhang Shengyan (Signature) Supervisor : LiKanshe (Signature) ABSTRACT Graphite with special weak interlayer strcture and excellent conductivity property,which make it become the common functional types material for polymer/inorganic layered nano-composite preparation, and correspondingly the polymer/graphite nano-composite functional type material has attracted more and more attention.According to the graphite easily caused agglomeration phenomenon and the problems that in the process of polymer/graphite nano-composite preparation.The graphite was organically modified at first, then taking solid shear mill method （ S3M ） for preparing partly graphite olefination PVC/graphite nanocomposite, which providing a simple, usful and easy for operation method, and as a possible way for graphene scale production.The experimental results are as follows: The structure of the PVC/graphite composite powder prepared by S3M and the correspondingly nano-composite material. The results showed that, under the strong three-dimensional shear stress field of pan-milling, friction, tensile, dislocation, extrusion chimeric,stretch slipping,shear peeling, grinding,mixed dispersion, realized graphite interlayer split and nano-composite with polymer.The XRD results indicate that, the graphite half-peak height and crystallite size are reduced obviously. The TEM showed that, after the treatment of solid shear mill, the graphite interlayer splited gradually, some crystal structure is destroyed and completely stripping, realized graphite olefination.The SEM results showed that, PVC/graphite composite powder with lamelliform shape characteristics, and lamellar elongted with the increasing milling times, the powder is more fuzziness, length-diameter ratio and diameter-thickness ratio larger, an