钴∕镍金属氢氧化物及四氧化三钴的制备及其超电容性能研究-物理化学专业论文.docxVIP

钴∕镍金属氢氧化物及四氧化三钴的制备及其超电容性能研究 钴∕镍金属氢氧化物及四氧化三钴的制备及其超电容性能研究 西北师范大学硕士学位论文化学化工学院谢莉婧 西北师范大学硕士学位论文 化学化工学院 谢莉婧 研究生:导 师: 研究生: 导 师: 专 业: 物理化学 研究方向: 新能源材料 III IV IV Abstract Super-capacitor is a new kind of energy storage devices with remarkable advantages. Electrode material is an important factor that affects the electrochemical performances. Therefore, the research and development of electrode materials has been a hot topic in both academic and industrial field in recent years. At present, Cobalt/nickel hydroxide and oxide have a potential application in the electrode materials of electrochemical capacitor due to their excellent electrochemical properties resulting from the good redox reaction activity and unique structure.This thesis was focused on the preparation of α-Co(OH)2、CoxNi1–x LDHs and Co3O4 and their applications as the electrode materials of electrochemical capacitors. Their morphologies, crystal structure and components were characterized by means of modern analysis techniques. The capacitive behaviors of the resultant materials were also measured by electrochemical skills. The main points of this thesis are summarized as follows: Sheet-like α-Co(OH)2 composed of the uniform nanoparticles was successfully prepared using cobalt chloride as the raw material and polyvinyl pyrrolidone as the dispersant by chemical precipitation method. The components of products were analyzed by FT-IR and the structure and morphology were characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM), respectively. The electrochemical performances were investigated by cyclic voltammetry and constant current charge/discharge techniques. The results show that an extraordinary high specific capacitance value of 1220 F/g was achieved, and the α-Co(OH)2 is a promising electrode material for supercapacitor A novel cobalt nickel double hydroxides (CoxNi1–x LDHs) nanoparticles are synthesized by chemical co-precipitation route using cobalt chloride and