光伏电池导电浆中玻璃粘结剂对提高光电转换效率的研究-材料学专业论文.docxVIP

东华大学硕士学位论文摘要 东华大学硕士学位论文 摘要 网络结构。 在确定 TeO2/PbO 为 2:1 摩尔比的条件下，进一步观察 TeO2-PbO- B2O3-Bi2O3-Li2O-RxOy 系统玻璃组成中 B2O3、Bi2O3 和 Li2O 等摩尔量 的变化对玻璃的结构、热学性能和电学性能等方面的影响。结果表明： 当 B2O3 为 12mol 时，Tg 出现最大值，而热膨胀系数（α）达到最小 值，出现“硼氧反常”现象；当 Bi2O3 含量在 2-10mol 范围内变化时， Tg 逐渐升高，α 逐渐降低，玻璃的介电常数和体积电阻率也逐渐增大； 当 Li2O 含量的 2.5-6.5mol 范围变化时，玻璃的转变温度和膨胀系数 增大，而介电常数减小，且高摩尔含量的 Li2O 有促进玻璃析晶的倾 向，经热处理后的玻璃生成 Bi2TeO5 和碲铋矿型晶体。 选择部分碲玻璃样品试制了导电银浆并应用于光伏电池上，研究 了玻璃组成的变化与光电转换效率之间的关系，并对导电浆料中玻璃 含量在 1-5wt%范围内的变化对光电转换效率的影响等进行了探讨。 其中，采用 2wt%的 T-10-2 玻璃样品制备出的电池最大光电转换效率 为 18.46%左右，达到了国际同类产品的先进水平。 关键词：低熔点玻璃，光电转换效率，转变温度，导电银浆，光伏电 池 ii 东华大学硕士学位论文AB 东华大学硕士学位论文 ABSTRACT PAGE PAGE iii RESEARCH ON THE GLASS BINDERS OF CONDUCTIVE PASTE TO IMPROVE THE PHOTOELECTRIC CONVERSION EFFICIENCY OF THE PHOTOVOLTAIC CELLS ABSTRACT Photovoltaic cells are one of the most widely used green energy at present. The lower contact resistivity generated from the screen-printed procedure between the conductive silver paste and silicon surface, the higher photoelectric conversion efficiency will be. The composition and property of the low- melting glass used in the silver paste is one of the most important factors that can determine the contact ohmicity. The study of tellurite glass system is a key link to improving the conversio n efficiency of the paste and developing high performance paste is significant to the our society and economy. In this paper, three different system of lead-bearing glass were studied on their glass transition temperature (Tg). The content of main oxides was changed to find the relation between composition and Tg temperature. The results show that the glass system with composition of 65-70mol% PbO, 8-12mol% B2O3, 6-14mol% ZnO, 3-6mol% Bi2O3, 1.5mol%SiO2 and 4-5mol% Li2O has a lower Tg temperature. Thus obtain the PbO-B2O3-ZnO-Bi2O3-Li2O-RxOy glass system as the based composition to add TeO2 into. The TeO2-PbO-B2O3-Bi2O3-Li2O-RxOy glass system was further prepared with the substitution of TeO2 for PbO content. The variation of Tg w