还原铬渣去除废水中磷和铬的研究-环境工程专业论文.docxVIP

摘 摘 要 第 第 II 页 还原铬渣对磷酸盐的去除率分别为 50.1%和 99.0%，溶液 pH 值能显著影响 除磷效果。实际水体中共存离子影响实验表明，NaNO3、Na2SO4 作为电解 - 2+ 质对除磷有促进作用；HCO3 既有促进作用又有抑制作用；水体中 Ca ， + Mg2+和 NH4 的存在对除磷有促进作用。 还原铬渣对模拟含 Cr(Ⅲ)废水的处理结果表明：在投加量为 2.5g/L 时， 两种还原铬渣对含 Cr(Ⅲ)浓度为 25mg/L~500mg/L 的模拟含铬废水都有较 好的去除效果，处理效率都超过 95%。还原铬渣对 Cr(Ⅲ)的去除机理主要 是靠沉淀作用，投加量越大，形成沉淀就越密实，残渣中铬的含量大，具 有作为铬矿重新回收利用铬的潜力。 关键词：铬渣，热解，除磷，除铬 AB ABSTRACT 第 第 III 页 STUDY OF PHOSPHATE AND CHROME IN WASTE WATER USING REDUCED CHROMIUM SLAG ABSTRACT Chrome pollution is a great environmental problem in China. There are many shortages in the treatment and disposal methods. Pyrolysis has becoming a promising treatment method in hexavalent chromium containing solid wastes, and has some advantage in chromium slag treatment. But there will be secondary pollution if the residual has not been treated well. The environmental safety of the reduced chromium slag pyrolysised under 600℃ and 800℃ has been proved. Then the reduced slag were used in treatment of phosphate and Cr(Ⅲ) in waste water. The effects of some factors, such as dosage and pH were investigated with the mechanisms of phosphate removal and Cr(Ⅲ) removal discussed, which provided a new solution for reutilization of reduced chromium slag. The results showed that the consist of chromium slag did not changed much during pyrolysis process, Cr(Ⅵ) has been reduced to Cr(Ⅲ). The leaching toxicity reduced dramatically. Chromium speciation results indicated that the pyrolysis process stabilized the chromium in the slag. The reduced chromium 第 第 PAGE VII 页 slag has a strong acid buffering capacity of over 10mol/kg. The column leaching study and long term performance testified the stabilization of reduced chromium slag and indicated the feasibility of reutilization of reduced chromium slag. The result of phosphate removal indicated that the treated samples had an effective treatment performance on phosphate removal. At the dosage of 600℃ and 800℃ reduced chromium slag 2.5g/L and initial phosphate concentratio