伊犁蒙其古尔铀矿床含矿层砂岩中高岭石形成机制及与铀成矿关系丁.DOCVIP

伊犁蒙其古尔铀矿床含矿层砂岩中高岭石形成机制及与铀成矿关系 丁波1，刘红旭1，蒋宏2，张虎军2，李平1，张宾1 （1. 中核集团铀资源勘查与评价重点实验室 核工业北京地质研究院 北京 100029； 2. 核工业二一六大队 乌鲁木齐 830011） 中核集团铀资源勘查与评价重点实验室 核工业北京地质研究院 北京 100029； 内容提要：伊犁盆地蒙其古尔铀矿床为典型的层间氧化带型铀矿床，虽然前人对该矿床含矿层砂岩中高岭石含量、成因及与铀成矿关系等方面开展了研究，但对高岭石及其共生矿物形成机制、高岭石与铀成矿关系等方面研究依然较为薄弱。本文为了研究蒙其古尔铀矿床含矿层砂岩中高岭石形成机制及与铀成矿关系，综合的应用了偏光显微镜、X-衍射、扫描电镜等手段，对其含矿层中高岭石含量、形貌特征进行了系统的研究，并对高岭石H-O同位素与碳酸盐胶结物C-O同位素进行了研究。研究表明：①含矿层普遍发育有强烈的高岭石化，其占黏土总量的58.0% ~ 93%，并以弱氧化带砂岩中高岭石含量最高；②高岭石主要呈泥晶状、层片状与蠕虫状的形式分布于砂岩粒间孔隙和长石溶蚀空隙中，共生矿物为自生石英、石膏、黄铁矿、铀矿物等；③高岭石DV-SMOW为-119.4 ‰~-48.3 ‰，18OV-SMOW为10.9 ‰~13.7 ‰，碳酸盐胶结物δ13CV-PDB为-10.9～-7.2‰，δ18OV-SMOW为17.6‰～24.9‰，表明高岭石是由富含CO2大气降水（无机）和煤系地层有机质脱羟基及热降解作用产生的有机酸及CH4等还原性气体（煤层气）（有机）与砂岩相互作用的产物，并认为高岭石及其共生矿物是在含矿层埋藏成岩过程中流体与岩石相互作用的结果；④高岭石与铀矿化除了存在直接吸附、间接还原关系，还存在成因上的联系，即高岭石和铀成矿皆是有机-无机流体与砂岩相互作用的结果。 关键词：伊犁盆地蒙其古尔铀矿床；高岭石；形成机制；铀成矿 The genetic mechanism of authideni kaolinte and its relationship with uranium minerization DING Bo， LIU Hongxu CNNC Key Laboratory of Uranium Resources Exploration and Evaluation Techniques Beijing Research Institute of Uranium Geology Beijing 100029 Abstract：The Mengqiguer uranium deposit was typical interlayer oxidation zone type uranium deposit and located in the southern margin area of Yili basin. Although the content, genesis of kaolinite and its relationship with uranium mineralization was studied by predecessor, the problem about the mechanism of kaolinite and its common minerals was still existed, especially about the relationship between kaolinite and uranium mineralization. In order to researching above problem, the methods of polarizing microscope, scanning electron microscope, electronic probe was comprehensively utilized to analysis the content and morphology of kaolinite in the ore-bearing layer systematically and the stable isotope of alteration mineral about kaolinite (H-O) and carbonate cement (C-O) was also studied. Four achievements can be obtained. Firstly, strong kaolinization with the content ranging between 58.0% to 93%was existed commonly in sands