静电纺丝纳米纤维膜基光化学传感器的制备与其在重金属检测.docVIP

静电纺丝纳米纤维膜基光化学传感器的制备及其在重金属检测中的应用的研究进展 乔逸群, 张 楠, 颜 娟, 王锡昌*, 钟 建* (上海海洋大学食品学院, 上海水产品加工及贮藏工程技术研究中心, 上海 201306) 摘 要: 化学传感器特别是光化学传感器已经被广泛研究, 并应用于检测目标物如食品中的重金属。静电纺丝纳米纤维膜由于具有高比表面积、高孔隙率、可控性良好和易功能化等特点, 可以被用来固定传感器以提高其灵敏度。本文主要综述静电纺丝纳米纤维膜基光化学传感器的制备及其在重金属离子检测中的应用进展。首先, 简单介绍光化学传感器及静电纺丝纳米纤维膜基光化学传感器, 随后根据其制备方法的差异分为高分子聚合物化学修饰法、高分子聚合物物理共混法、纳米纤维化学修饰方法和纳米纤维物理吸附方法4类, 并分别综述其制备得到的静电纺丝纳米纤维膜基光化学传感器应用于重金属检测的进展, 这4类方法各有优劣势, 都具有较好的应用前景。本文将为静电纺丝纳米纤维膜基光化学传感器用于目标物的检测提供指导。 关键词: 静电纺丝技术; 纳米纤维; 光化学传感器; 重金属; 检测 Research progress on preparation of electrospun nanofibrous membrane-immobilized optical chemosensors and their applications in heavy metals detection QIAO Yi-Qun, ZHANG Nan, YAN Juan, WANG Xi-Chang*, ZHONG Jian* (Shanghai Engineering Research Center of Aquatic-Product Processing Preservation, College of Food Science Technology, Shanghai Ocean University, Shanghai 201306, China) ABSTRACT: Chemosensors, especially optical chemosensors, have been widely investigated for rapid detection of analytes such as heavy metals in food. In order to improve the detection sensitivity, electrospun nanofibrous membranes (ENMs) have been recently explored for the immobilization of chemosensors due to their high surface-to-volume ratio, high porosity, controllability of nanofiber properties, and easiness of functionalization. This review summarized the preparation of ENM-immobilized optical chemosensors and their applications in heavy metals detection. Firstly, optical chemosensors and ENM-immobilized optical chemosensors were introduced. Then, the preparation methods of ENM-immobilized optical chemosensors were classified into four types: polymer-based chemical modification, polymer-based physical blending, nanofiber-based chemical modification, and nanofiber-based physical adsorption. The application progresses of the four types of ENM-immobilized optical chemosensors for heavy metals detection were reviewed. These four methods have their advantages and disadvantages and own good application prospects. T