液体核磁共振中基于偶极场理论的扩散行为模拟-福州大学学报.PDF

36 2 ( ) Vo.l 36 No. 2 2008 4 Journal ofFuzhouUniversity(NaturalScience) pr. 2008 : 1000- 2243( 2008) 02- 0208- 05 1 2 2 , , ( 1. , 350002; 2. , 361005) : CR ZED . , . . : ; ; ; : O641 : Simulation of diffusion behaviors in liquid NMR based on dipolar field theory 1 2 2 ZENG Qun- ying, LIN Q iao- ling, C I Shu- hui ( 1. College of Physics and Information Engineering, Fuzhou University, Fuzhou, Fujian 350002, China; 2. Department ofPhysics, XiamenUniversity, X iamen, Fujian 361005, China) Abstract: In this paper, theoretical expressions of nonlinear evolution were derived for two- compo- nent homonuclear spin system under the COSY- revamped by asymmetric Z gradient echo detection (CR ZED) pulse sequence from the combination of the dipolar field theory and productoperator for- malism. Computer smi ulations based on the random walk model and dipolar field theory were per- formed to gain insight into thenonlinear evolution properties of free- diffusion one- and two- compo- nent spin systems. The smi ulation results agreewellw ith theoretical predictions. Keywords: NMR; dipolar field; diffusion; smi ulation [ 1] , (MSEs) ( iMQC) [2] . , . [3] 90, . , , , [4] [4- 6] . . , . 1 J I= 1/2 S= 1/2 , IS ( I= 1/2). 1, ( P/2) x