二次水热法制备鸟巢状TiO2Co3O4纳米结构及其锂电性能.docVIP

二次水热法制备鸟巢状Ti02/Co304纳 米结构及其锂电性能 张冠群许州刘建雄杨艳蓉刘成程琪于晓华 昆明理工大学材料科学与工程学院华南理工大学材 料科学与工程学院昆明理工大学固体废弃物资源化 家工程研宄中心 家工程研宄中心 摘要： 以TiO2粉末和NaOH为原料，在机械外力场作用下，采用水热法制备TiO2纳米 线。随后将得到的TTiO2纳米线与六水合硝酸钴(Co (N03) 2.6H20)和尿素(Urea) 共同水热反应制备Ti02/Co304纳米结构材料。分别利用X射线衍射仪(XRD)、 扫描电子显微镜(SEM)、电池充放电测试仪和电化学工作站等，对材料的相组 成、微观形貌、锂电性能和阻抗性能进行测试。结果表明，Ti02/CoA纳米复合 材料为鸟巢状结构，其在33. 5mA/g电流密度下恒电流充放电的首次放电容量为 777mAh/g,充电容量为759mAh/g, 100次循环后的可逆容量仍保持在663mAh/g, 具有良好的循环稳定性和电化学待性。 关键词： 锂离了电池;电化学性能;循环稳定性;鸟巢状;Ti02纳米线;Ti02/Co304复 合材料;二次水热法; 作者简介：张冠群:女，1991年生，硕士，研宄方向为Ti02纳米结构的锂电性 能 E-mail:zhangguan_qun@126. com 作者简介：刘建雄:男，1962年生，教授，研究方向为金屌材料加工 E-mai1:1jx5192665@163. com 作者简介：于晓华:男，1986年生，博士，研究方向为材料热力学 E-mail:xiaohua HYPERLINK mailto:y@163.comy@163.com 基金：国家自然科学基金51665022) Two-step Hydrothermally Synthesized Nest-like Ti02/Co304 Nanostructures with Good Electrochemical Performance for Lithium Ion Battery ZHANG Guanqun XU Zhou LIU Jianxiong YANG Yanrong LIU Cheng CHENG Qi YU Xiaohua Faculty of Materials Science and Engineering, Kunming University of Science and Technology; National Engineering Research Center of Waste Resource Recovery, Kunming University of Science and Technology; Abstract： Tn this work, a Ti02/Co304 nanostructured materials was prepared through a hydrothermal process using cobalt (II) nitrate hexahydrate, urea, and hydrothermally pre-synthesized (from Ti02 powders and NaOH and under mechanical stirring) TiO2 nanowires as raw materials. The composition, morphology and electrochemical performance of the product were characterized by employing X-ray diffractometer (XRD) , scanning electron microscope (SEM) , charging/discharging tester and electrochemical workstation. Our experiments illustrated the nest-like micromorphology, good cyclic stability and electrochemical character of this two-step hydrothermally synthesized Ti02/Co304 composites, as the electrode exhibited initial discharge and charge capacities of 777 mAh/g and 759 mAh/g, respectively, and a capacity retention of 663 mAh/g after 100