介孔二氧化硅的制备及银的负载性.docxVIP

南京理工大学 硕士学位论文 介孔二氧化硅的制备及银的负载性研究 姓名：杨冲 申请学位级别：硕士 专业：材料学 指导教师：刘孝恒硕上论文 介孔二氣化砝的制备及银的负载性研究 硕上论文 介孔二氣化砝的制备及银的负载性研究  PAGE \* MERGEFORMAT II  PAGE \* MERGEFORMAT # 摘 要 近年来，介孔材料由于其独特的优异性能成为了研究开发的热点，在催化、吸附 分离、药物释放等领域的应用前景更使其备受关注。本文主要研究采用溶胶-凝胶法 制备分布均匀、形状规则的介孔二氧化硅并对其进行改性，研究改性后复合的介孔二 氧化硅的性质。以正硅酸乙酯（TEOS)作为硅源、十六烷基三甲基溴化铵（CTAB) 作为模板，在醇水体系中，在碱性条件下合成分布均勻的球形介孔状二氧化硅(Si02), 通过一系列表征手段对介孔二氧化硅进行表征；同时将制备的介孔二氧化硅作为载 体，将金属银（Ag)粒子在介孔二氧化硅上进行负载掺杂改性，研究改性后复合结 构新的性质及应用。主要研究内容如下： 在碱性条件下以阳离子表面活性剂十六烷基三甲基溴化铵（CTAB)作为模 板，制备分布均匀、形状规则的球形介孔二氧化硅，采用X-射线衍射（XRD)、比表 面分析仪（BET)、热重分析（TG)、扫描电子显微镜（SEM)、透射电子显微镜（TEM) 等多种手段对制备的介孔Si02纳米粒子进行表征。 研究表面活性剂、醇、煅烧温度等对介孔形成过程的影响，解释溶胶-凝胶 法制备球形介孔Si02的形成机理，并得出制备形状规则、分布均勻的介孔Si02球的 最优条件。 将制备的介孔二氧化硅球作为载体，通过直接和间接的合成方法将银负载 到介孔二氧化硅球的孔道以及表面，得到银负载型介孔二氧化硅，比较得出最佳的制 备方法，并对改性后形成的Ag-Si02进行表征。 将金属Ag改性后的介孔Si02进行抗菌实验，研究其对大肠杆菌的抗菌效 果，结果显示其具有优于纳米银（Ag)的抗菌作用，实验初步阐述改性后Ag-Si02 的抗菌机理。 关键词：溶胶-凝胶，银，介孔二氧化硅，抗菌性能，大肠杆菌 硕上论文 Abstract Abstract Recently, mesoporous materials have been an important approach to the development of their unique excellent properties, and have broad application in many fields, such as catalysis, adsorption and separation, drug delivery and other fields. In this paper the mesoporous silicas with well distribution and rule shape were prepared by sol-gel, at the same time we modified the mesoporous materials and their properties had also been studied. The mesoporous silicas with uniform size had been prepared by sol-gel using TEOS and CTAB as raw materials under the alcohol-water system. The influences of the reaction conditions were discussed and a possible mechanism for the formation of the mesoporous silicas is proposed. The main contents were summarized as following: Mesoporous silicas were prepared with cationic surfactant as template. XRD, TG, BET, SEM, TEM were been used in the characterization of these spheres. The effects of difference conditions on the reaction, such as the type of surfactants, the dosage of the alcohol, calcination temperature were discussed and the